Aquanitrilotris(methylenephosphonato)bis(dimercury(I)) Hydrate, [(Hg2)2(H2O) N(CH2PO3)3H2]•H2O: Synthesis, Structure, and Properties

被引：1
|
作者：
Somov, N. V. [1 ]
Chausov, F. F. [2 ,3 ]
Zakirova, R. M. [3 ]
Shumilova, M. A. [4 ]
Aleksandrov, V. A. [4 ]
Petrov, V. G. [4 ]
机构：
[1] NI Lobachevskii State Univ, Nizhnii Novgorod, Russia
[2] Russian Acad Sci, Ural Branch, Physical Tech Inst, Izhevsk, Russia
[3] Udmurt State Univ, Izhevsk, Russia
[4] Russian Acad Sci, Inst Mech, Ural Branch, Izhevsk, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2016年 / 42卷 / 01期
关键词：
VIBRATIONAL-SPECTRA; CRYSTAL-STRUCTURE; THERMAL-BEHAVIOR; COMPLEXES; PHOSPHONATES; MERCURATION; CHEMISTRY; PHOSPHATE;
D O I：
10.1134/S107032841601005X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A reaction of dimercury(I) dinitrate with nitrilotris(methylenephosphonic acid), N(CH2PO3)(3)H-6, gave the complex [(Hg-2)(2)(H2O){N(CH2PO3)(3)H-2}] center dot H2O. The crystals of the complex are triclinic, space group P (1) over bar Z = 2, a = 8.3436(3), b = 9.0744(3), c = 11.1124(4) angstrom, a = 91.875(3)degrees, beta= 104.452(3)degrees, gamma = 92.195(3)degrees (CIF file CCDC no. 1051860). The atoms of either dimercury cation are coordinated differently, making up a distorted tetrahedron and a distorted trigonal bipyramid. The ligand is coordinated to the Hg atoms through seven donor atoms: six (out of nine) O atoms and a N atom. The coordination involves the formation of chelate rings: two four-membered, three five-membered, a six-membered, and an eight-membered ring.
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页码：37 / 43
页数：7
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