C-H and C-F coordination of arenes in neutral alkaline earth metal complexes

被引：12

作者：

McMullen, Jacob S. ^{[1
]}

Edwards, Alison J. ^{[2
]}

Hicks, Jamie ^{[1
]}

机构：

[1] Australian Natl Univ, Res Sch Chem, Canberra, ACT 2601, Australia

[2] Australian Nucl Sci & Technol Org, Australian Ctr Neutron Scattering, Sydney, NSW 2234, Australia

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 25期

基金：

澳大利亚研究理事会;

关键词：

Alkaline earth metals - Coordination reactions - Calcium compounds - Magnesium compounds;

D O I：

10.1039/d1dt01532j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of neutral magnesium and calcium complexes bearing an extremely bulky diamido ligand have been synthesised and crystallographically characterised. A number of these complexes feature rare group 2 metalMIDLINE HORIZONTAL ELLIPSISaromatic interactions, such as the eta(6)-coordination of benzene and 'agostic-like' C-H coordination, the latter previously unseen in neutral Mg and Ca complexes.

引用

页码：8685 / 8689

页数：5

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