Synthesis of fluoro(aryloxo)alkaline earth metal cages by C-F bond activation

被引：7
|
作者：
Deacon, Glen B. [1 ]
Junk, Peter C. [1 ]
Moxey, Graeme J. [1 ]
机构：
[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
来源：
DALTON TRANSACTIONS | 2010年 / 39卷 / 24期
基金：
澳大利亚研究理事会;
关键词：
ARYL-CALCIUM; COORDINATION; COMPLEXES; REAGENTS; LIGANDS; HALIDES;
D O I：
10.1039/c0dt00122h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of Ca or Sr metal with Hg(C(6)F(5))(2) and 2,4,6-trimethylphenol (HOmes) in 1,2-dimethoxyethane (dme) at room temperature resulted in C-F bond activation, giving rise to the unique fluoro(aryloxo)alkaline earth cages [Ca(5)(mu(4)-F)(mu(3)-F)(4)(mu-Omes)(4)(Omes)(dme)(4)] 1 and [Sr(10)(mu(4)-F)(4)(mu(3)-F)(4)(mu-Omes)(12)(dme)(4)] 2, which can be viewed as arrested fluorite structures.
引用
收藏
页码：5620 / 5622
页数：3
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