Triterpenoid saponins from Thalictrum minus L -: Part IX -: The elucidation of the structure of thalicoside F, a minor oleanane glycoside from Thalictrum minus L

被引：10
|
作者：
Gromova, AS
Lutsky, VI
Semenov, AA
Li, D
Owen, NL [1 ]
机构：
[1] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA
[2] Russian Acad Sci, Inst Organ Chem, Siberian Branch, Irkutsk 664033, Russia
来源：
PHYTOCHEMISTRY | 1998年 / 47卷 / 03期
关键词：
Thalictrum minus L; Ranunculaceae; triterpenoid saponins; oleanane; thalicoside F; NMR spectra;
D O I：
10.1016/S0031-9422(97)00574-8
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
new triterpenoid saponin, thalicoside F was isolated from the above-ground part of Thalictrum minus L. (Ranunculaceae family) collected in Eastern Siberia (Russia). The structure of thalicoside F was elucidated by a combination of 1D- and 2D-NMR spectroscopy and mass spectroscopy, and was determined to be C(47)H(74)O(17){3-beta-O[alpha-L-rhamnopyranosyl-(1-->2)-beta-D-glucopyranosyl-(1-->4)-alpha-L-arabiopyranosyl]-11 alpha,12 alpha-epoxyoleanane-28,13 beta-olide}. (C) 1997 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：437 / 440
页数：4
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