Triterpenoid saponins from Thalictrum minus L -: Part IX -: The elucidation of the structure of thalicoside F, a minor oleanane glycoside from Thalictrum minus L

被引：10
|
作者：
Gromova, AS
Lutsky, VI
Semenov, AA
Li, D
Owen, NL [1 ]
机构：
[1] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA
[2] Russian Acad Sci, Inst Organ Chem, Siberian Branch, Irkutsk 664033, Russia
来源：
PHYTOCHEMISTRY | 1998年 / 47卷 / 03期
关键词：
Thalictrum minus L; Ranunculaceae; triterpenoid saponins; oleanane; thalicoside F; NMR spectra;
D O I：
10.1016/S0031-9422(97)00574-8
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
new triterpenoid saponin, thalicoside F was isolated from the above-ground part of Thalictrum minus L. (Ranunculaceae family) collected in Eastern Siberia (Russia). The structure of thalicoside F was elucidated by a combination of 1D- and 2D-NMR spectroscopy and mass spectroscopy, and was determined to be C(47)H(74)O(17){3-beta-O[alpha-L-rhamnopyranosyl-(1-->2)-beta-D-glucopyranosyl-(1-->4)-alpha-L-arabiopyranosyl]-11 alpha,12 alpha-epoxyoleanane-28,13 beta-olide}. (C) 1997 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：437 / 440
页数：4
相关论文
共 37 条
  • [1] New triterpenoid glycosides from Thalictrum minus L.: 11.: Structure of thalicoside H1
    Trofimova, NN
    Gromova, AS
    Lutsky, VI
    Semenov, AA
    Avilov, SA
    Li, D
    Owen, NL
    RUSSIAN CHEMICAL BULLETIN, 1999, 48 (03) : 596 - 599
  • [2] TRITERPENE SAPONINS FROM THALICTRUM-MINUS .7. STRUCTURE OF THALICOSIDE-E
    GROMOVA, AS
    LUTSKII, VI
    ZINCHENKO, SV
    GANENKO, TV
    SEMENOV, AA
    KHIMIYA PRIRODNYKH SOEDINENII, 1993, (04): : 567 - 571
  • [3] TRITERPENE SAPONINS FROM THALICTRUM-MINUS .8. STRUCTURE OF THALICOSIDE-D
    GROMOVA, AS
    SEMENOV, AA
    LUTSKII, VI
    ZINCHENKO, SV
    TROFIMOVA, NN
    RASHKES, YV
    KHIMIYA PRIRODNYKH SOEDINENII, 1994, (03): : 398 - 403
  • [4] TRITERPENE SAPONINS FROM THALICTRUM-MINUS .6. STRUCTURE OF THALICOSIDE-C
    GROMOVA, AS
    LUTSKII, VI
    ZINCHENKO, SV
    TROFIMOVA, NN
    SEMENOV, AA
    NAKHOVA, NA
    KHIMIYA PRIRODNYKH SOEDINENII, 1993, (01): : 103 - 109
  • [5] TRITERPENE SAPONINS FROM THALICTRUM-MINUS .5. STRUCTURE OF THALICOSIDE-B
    GROMOVA, AS
    LUTSKY, VI
    SEMENOV, AA
    VALEEV, RB
    KALABIN, GA
    ELKIN, YN
    KHIMIYA PRIRODNYKH SOEDINENII, 1985, (05): : 670 - 676
  • [6] MINOR ALKALOIDS FROM THALICTRUM MINUS
    SIDJIMOV, A
    CHRISTOV, V
    GROZEVA, A
    DOKLADI NA BOLGARSKATA AKADEMIYA NA NAUKITE, 1992, 45 (11): : 63 - 66
  • [7] New Flavonoid Glycoside from Thalictrum minus
    B. D. Komilov
    M. A. Agzamova
    I. M. Isaev
    K. A. Eshbakova
    Chemistry of Natural Compounds, 2020, 56 : 814 - 816
  • [8] MINOR ALKALOIDS FROM THALICTRUM-MINUS
    SIDJIMOV, AK
    CHRISTOV, VS
    JOURNAL OF NATURAL PRODUCTS, 1984, 47 (02): : 387 - 387
  • [9] TRITERPENE SAPONIN FROM THALICTRUM-MINUS .4. THE STRUCTURE OF THALICOSIDE-A
    GROMOVA, AS
    LUTSKY, VI
    SEMENOV, AA
    DENISENKO, VA
    ISAKOV, VV
    KHIMIYA PRIRODNYKH SOEDINENII, 1984, (02): : 213 - 219
  • [10] TRITERPENE GLUCOSIDES FROM THALICTRUM-FOETIDUM L AND THALICTRUM-MINUS L AND THEIR ANTINEOPLASTIC ACTIVITY
    RAKHIMOV, KD
    VERMENICHEV, SM
    LUTSKY, VI
    GROMOVA, AS
    GANENKO, TV
    SEMENOV, AA
    KHIMIKO-FARMATSEVTICHESKII ZHURNAL, 1987, 21 (12): : 1434 - 1436
1234