Synthesis and characterization of boric acid mediated metal-organic frameworks based on trimesic acid and terephthalic acid

被引：18
|
作者：
Ozer, Demet [1 ]
Kose, Dursun A. [2 ]
Sahin, Onur [3 ]
Oztas, Nursen Altuntas [1 ]
机构：
[1] Hacettepe Univ, Dept Chem, Ankara, Turkey
[2] Hitit Univ, Dept Chem, Corum, Turkey
[3] Sinop Univ, Sci & Technol Res Applicat & Res Ctr, Sinop, Turkey
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2017年 / 1141卷
关键词：
Boric acid; Sodium; Trimesic acid; Terephthalic acid; B-MOF; STABILITY; CHEMISTRY; SORPTION; MOF-5;
D O I：
10.1016/j.molstruc.2017.03.120
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The new metal-organic framework materials based on boric acid reported herein. Sodium and boron containing metal-organic frameworks were synthesized by one-pot self-assembly reaction in the presence of trimesic acid and terephthalic acid in water/ethanol solution. Boric acid is a relatively cheap boron source and boric acid mediated metal-organic framework prepared mild conditions compared to the other boron source based metal-organic framework. The synthesized compounds were characterized by FT-IR, p-XRD, TGA/DTA, elemental analysis, C-13-MAS NMR, B-11-NMR and single crystal measurements. The molecular formulas of compounds were estimated as C18H33B2Na5O28 and C8H24B2Na2O17 according to the structural analysis. The obtained complexes were thermally stable. Surface properties of inorganic polymer complexes were investigated by BET analyses and hydrogen storage properties of compound were also calculated. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：261 / 267
页数：7
相关论文
共 50 条
  • [41] Synthesis and characterization of holmium based metal-organic frameworks
    Abbas, Muhammad
    Degani, Murtaza
    Sheybani, Simin
    Shah, Tejas
    Joy, Monu
    Balkus Jr, Kenneth J.
    CRYSTENGCOMM, 2024, 26 (39) : 5567 - 5573
  • [42] Structural diversity of metal-organic frameworks based on a chalcone dicarboxylic acid ligand
    Xu, Hao
    Zeng, Xianghua
    Pan, Wei
    Zhang, Junyong
    Cao, Yangzheng
    Guo, Haiyang
    Xie, Jingli
    Dalton Transactions, 2020, 49 (18): : 5783 - 5786
  • [43] Structural diversity of metal-organic frameworks based on a chalcone dicarboxylic acid ligand
    Xu, Hao
    Zeng, Xianghua
    Pan, Wei
    Zhang, Junyong
    Cao, Yangzheng
    Guo, Haiyang
    Xie, Jingli
    DALTON TRANSACTIONS, 2020, 49 (18) : 5783 - 5786
  • [44] Construction of boric acid-functionalized metal-organic frameworks for glycopeptide recognition in the serum of cervical cancer patients
    Rao, Dongping
    Wang, Baichun
    Zhong, Huizhen
    Yan, Yinghua
    Ding, Chuan-Fan
    RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2022, 36 (13)
  • [45] Stable metal-organic framework developed from zinc oxide and terephthalic acid
    不详
    MRS BULLETIN, 2000, 25 (02) : 6 - 6
  • [46] Metal-organic frameworks as catalysts for the conversion of methane to acetic acid
    Phan, Anh
    Yaghi, Omar
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
  • [47] Preparation and applications of metal-organic frameworks composed of sulfonic acid
    Yoo, Dong Kyu
    Lee, Gyudong
    Mondol, Md. Mahmudul Hassan
    Lee, Hye Jin
    Kim, Chang Min
    Jhung, Sung Hwa
    COORDINATION CHEMISTRY REVIEWS, 2023, 474
  • [48] Towards hydroxamic acid linked zirconium metal-organic frameworks
    Pereira, Carla F.
    Howarth, Ashlee J.
    Vermeulen, Nicolaas A.
    Almeida Paz, Filipe A.
    Tome, Joao P. C.
    Hupp, Joseph T.
    Farha, Omar K.
    MATERIALS CHEMISTRY FRONTIERS, 2017, 1 (06) : 1194 - 1199
  • [49] Cooperative Protonation Underlying the Acid Response of Metal-Organic Frameworks
    Xu, Yan
    Yang, Shuai-Liang
    Li, Gen
    Bu, Ran
    Liu, Xiao-Yan
    Gao, En-Qing
    CHEMISTRY OF MATERIALS, 2022, 34 (12) : 5500 - 5510
  • [50] Characterization of Lewis Acid Sites in Metal-Organic Frameworks Using Density Functional Theory
    Liu, Dahuan
    Zhong, Chongli
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2010, 1 (01): : 97 - 101
12345