Synthesis and characterization of boric acid mediated metal-organic frameworks based on trimesic acid and terephthalic acid

被引：18
|
作者：
Ozer, Demet [1 ]
Kose, Dursun A. [2 ]
Sahin, Onur [3 ]
Oztas, Nursen Altuntas [1 ]
机构：
[1] Hacettepe Univ, Dept Chem, Ankara, Turkey
[2] Hitit Univ, Dept Chem, Corum, Turkey
[3] Sinop Univ, Sci & Technol Res Applicat & Res Ctr, Sinop, Turkey
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2017年 / 1141卷
关键词：
Boric acid; Sodium; Trimesic acid; Terephthalic acid; B-MOF; STABILITY; CHEMISTRY; SORPTION; MOF-5;
D O I：
10.1016/j.molstruc.2017.03.120
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The new metal-organic framework materials based on boric acid reported herein. Sodium and boron containing metal-organic frameworks were synthesized by one-pot self-assembly reaction in the presence of trimesic acid and terephthalic acid in water/ethanol solution. Boric acid is a relatively cheap boron source and boric acid mediated metal-organic framework prepared mild conditions compared to the other boron source based metal-organic framework. The synthesized compounds were characterized by FT-IR, p-XRD, TGA/DTA, elemental analysis, C-13-MAS NMR, B-11-NMR and single crystal measurements. The molecular formulas of compounds were estimated as C18H33B2Na5O28 and C8H24B2Na2O17 according to the structural analysis. The obtained complexes were thermally stable. Surface properties of inorganic polymer complexes were investigated by BET analyses and hydrogen storage properties of compound were also calculated. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：261 / 267
页数：7
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