Ionic Liquid (IL) Laden Metal-Organic Framework (IL-MOF) Electrolyte for Quasi-Solid-State Sodium Batteries

被引：55
|
作者：
Yu, Xingwen [1 ,2 ]
Grundish, Nicholas S. [1 ,2 ]
Goodenough, John B. [1 ,2 ]
Manthiram, Arumugam [1 ,2 ]
机构：
[1] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA
[2] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
来源：
ACS APPLIED MATERIALS & INTERFACES | 2021年 / 13卷 / 21期
关键词：
electrochemical energy storage; sodium batteries; quasi-solid-state electrolyte; metal-organic framework; ionic liquid; ENERGY-STORAGE; NANOPARTICLES; INTERFACES;
D O I：
10.1021/acsami.1c02563
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
An ionic liquid (IL) laden metal-organic framework (MOF) sodium-ion electrolyte has been developed for ambient-temperature quasi-solid-state sodium batteries. The MOF skeleton is designed according to a UIO-66 (Universitetet i Oslo) structure. A sodium sulfonic (-SO3Na) group grafted to the UIO-based MOF ligand improves the Na+-ion conductivity. Upon lading with a sodium-based ionic liquid (Na-IL), sodium bis(trifluoromethylsulfonyl)imide (NaTFSI) in 1-n-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide (Bmpyr-TFSI), the Na-IL laden sulfonated UIO-66 (UIOSNa) quasi-solid electrolyte exhibits a Na+-ion conductivity of 3.6 x 10(-4) S cm(-1) at ambient temperature. Quasi-solid-state sodium batteries with the Na-IL/UIOSNa electrolyte are demonstrated with a layered Na3Ni1.5TeO6 cathode and sodium-metal anode. The quasi-solid-state Na vertical bar vertical bar Na-IL/UIOSNa vertical bar vertical bar Na3Ni1.5TeO6 cells show remarkable cycling performance.
引用
收藏
页码：24662 / 24669
页数：8
相关论文
共 50 条
  • [1] Bioinspired design of vascularized glassy metal-organic frameworks electrolyte for quasi-solid-state sodium batteries
    Yan, Yingchun
    Liu, Zheng
    Li, Weining
    Feng, Fan
    Yang, Xinhou
    Qi, Bin
    Gong, Min
    Li, Zhiyuan
    Wang, Changqing
    Wei, Tong
    Fan, Zhuangjun
    ENERGY STORAGE MATERIALS, 2025, 74
  • [2] Ionic Liquid-Incorporated Metal-Organic Framework with High Magnesium Ion Conductivity for Quasi-Solid-State Magnesium Batteries
    Wei, Zhixuan
    Maile, Ruben
    Riegger, Luise M.
    Rohnke, Marcus
    Mueller-Buschbaum, Klaus
    Janek, Juergen
    BATTERIES & SUPERCAPS, 2022, 5 (12)
  • [3] Flexible Quasi-Solid-State Composite Electrolyte Membrane Derived from a Metal-Organic Framework for Lithium-Metal Batteries
    Liu, Li
    Sun, Chunwen
    CHEMELECTROCHEM, 2020, 7 (03): : 707 - 715
  • [4] Ionic Conduction Mechanism and Design of Metal-Organic Framework Based Quasi-Solid-State Electrolytes
    Hou, Tingzheng
    Xu, Wentao
    Pei, Xiaokun
    Jiang, Lu
    Yaghi, Omar M.
    Persson, Kristin A.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (30) : 13446 - 13450
  • [5] Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries
    Mirandona-Olaeta, Alexander
    Goikolea, Eider
    Lanceros-Mendez, Senentxu
    Fidalgo-Marijuan, Arkaitz
    de Larramendi, Idoia Ruiz
    BATTERIES-BASEL, 2023, 9 (12):
  • [6] A Quasi-Solid-State Polyether Electrolyte for Low-Temperature Sodium Metal Batteries
    Zhao, Tong
    Zheng, Xueying
    Wang, Donghai
    Huang, Liqiang
    Li, Bin
    Liu, Xuyang
    Yang, Hao
    Dai, Yiming
    Huang, Yunhui
    Luo, Wei
    ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (48)
  • [7] Preparation of poly(ionic liquid) composite quasi-solid electrolyte by incorporating metal-organic framework filler decorated with ionic liquid for lithium batteries
    Niu, Huizhe
    Zhang, Nan
    Ding, Minling
    Hou, Tongtong
    Zhang, Donghao
    Wang, Le
    Guan, Ping
    Hu, Xiaoling
    SOLID STATE IONICS, 2022, 380
  • [8] Understanding Reduced CO2 Uptake of Ionic Liquid/Metal-Organic Framework (IL/MOF) Composites
    Xia, Xiaoxiao
    Hu, Guoqing
    Li, Wei
    Li, Song
    ACS APPLIED NANO MATERIALS, 2019, 2 (09) : 6022 - 6029
  • [9] Ionic liquid assisted quasi-solid-state polymer electrolyte for rechargeable lithium metal batteries operating at room temperature
    Yuan, Yan
    Xue, Kesi
    Ma, Yitian
    Peng, Xiuping
    Wang, Bin
    Liu, Xuyi
    Liu, Manbo
    Song, Yonghui
    Lu, Hai
    ELECTROCHIMICA ACTA, 2023, 440
  • [10] Ionic covalent organic framework based quasi-solid-state electrolyte for high-performance lithium metal battery
    Tan, Xueling
    Zhong, Juanqi
    Tong, Yongfen
    Guo, Lin
    Xie, Yu
    Zhao, Jinsheng
    POLYMER, 2025, 317
12345