Ionic Liquid (IL) Laden Metal-Organic Framework (IL-MOF) Electrolyte for Quasi-Solid-State Sodium Batteries

被引：55
|
作者：
Yu, Xingwen [1 ,2 ]
Grundish, Nicholas S. [1 ,2 ]
Goodenough, John B. [1 ,2 ]
Manthiram, Arumugam [1 ,2 ]
机构：
[1] Univ Texas Austin, Mat Sci & Engn Program, Austin, TX 78712 USA
[2] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
来源：
ACS APPLIED MATERIALS & INTERFACES | 2021年 / 13卷 / 21期
关键词：
electrochemical energy storage; sodium batteries; quasi-solid-state electrolyte; metal-organic framework; ionic liquid; ENERGY-STORAGE; NANOPARTICLES; INTERFACES;
D O I：
10.1021/acsami.1c02563
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
An ionic liquid (IL) laden metal-organic framework (MOF) sodium-ion electrolyte has been developed for ambient-temperature quasi-solid-state sodium batteries. The MOF skeleton is designed according to a UIO-66 (Universitetet i Oslo) structure. A sodium sulfonic (-SO3Na) group grafted to the UIO-based MOF ligand improves the Na+-ion conductivity. Upon lading with a sodium-based ionic liquid (Na-IL), sodium bis(trifluoromethylsulfonyl)imide (NaTFSI) in 1-n-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide (Bmpyr-TFSI), the Na-IL laden sulfonated UIO-66 (UIOSNa) quasi-solid electrolyte exhibits a Na+-ion conductivity of 3.6 x 10(-4) S cm(-1) at ambient temperature. Quasi-solid-state sodium batteries with the Na-IL/UIOSNa electrolyte are demonstrated with a layered Na3Ni1.5TeO6 cathode and sodium-metal anode. The quasi-solid-state Na vertical bar vertical bar Na-IL/UIOSNa vertical bar vertical bar Na3Ni1.5TeO6 cells show remarkable cycling performance.
引用
收藏
页码：24662 / 24669
页数：8
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