Photochemical reactions of oligosilanes with C-60

被引：0
|
作者：
Kusakawa, T [1 ]
Ando, W [1 ]
机构：
[1] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN
来源：
ORGANOMETALLICS | 1997年 / 16卷 / 19期
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D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Photolyses of tert-butyl-substituted disilanes 1a-d with C-60 result in the formation of 1,16-adducts 2. The unusual products 3, and 5-7, in which the silyl and phenyl groups are attached on the 1,2-positions of C-60, also are obtained in the reactions of 1e and 4 with C-60 A free silyl radical process is suggested for these conversions on the basis of experiments with other di-and oligosilanes.
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页码：4027 / 4029
页数：3
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