Photochemical reactions of oligosilanes with C-60

被引：0

作者：

Kusakawa, T ^{[1
]}

Ando, W ^{[1
]}

机构：

[1] UNIV TSUKUBA,DEPT CHEM,TSUKUBA,IBARAKI 305,JAPAN

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 19期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Photolyses of tert-butyl-substituted disilanes 1a-d with C-60 result in the formation of 1,16-adducts 2. The unusual products 3, and 5-7, in which the silyl and phenyl groups are attached on the 1,2-positions of C-60, also are obtained in the reactions of 1e and 4 with C-60 A free silyl radical process is suggested for these conversions on the basis of experiments with other di-and oligosilanes.

引用

页码：4027 / 4029

页数：3

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