Synthesis of (S)-(+)-α-methoxymethyldihydro-coumarin:: Absolute configuration of the reduced product in enantioselective radical-mediated reduction

被引：0
|
作者：
Murakata, M [1 ]
Tsutsui, H [1 ]
Hoshino, O [1 ]
机构：
[1] Sci Univ Tokyo, Fac Pharmaceut Sci, Shinjuku Ku, Tokyo 162, Japan
来源：
HETEROCYCLES | 1997年 / 46卷
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D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
(S)-(+)-alpha-Methoxymethyldihydrocoumarin was synthesized starting from (R)-2-benzyl-3-hydroxypropyl acetate. Consequently, the absolute configuration of the reduced product obtained by radical-mediated reduction of alpha-iodo-alpha-methoxymethyldihydrocoumarin was determined to be R.
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页码：517 / 522
页数：6
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