Zirconium borohydride - A versatile reducing agent for the reduction of electrophilic and nucleophilic substrates

被引：16

作者：

Narasimhan, S ^{[1
]}

Balakumar, R ^{[1
]}

机构：

[1] SPIC Sci Fdn, Ctr Agrochem Res, Madras 600032, Tamil Nadu, India

来源：

SYNTHETIC COMMUNICATIONS | 2000年 / 30卷 / 23期

关键词：

D O I：

10.1080/00397910008087061

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Zirconium borohydride, a potential reducing agent, reduces acids, esters, imines to the corresponding alcohols and secondary amines in good yield at room temperature within two hours. This facile reducing property was taken advantage off in the synthesis of pheromones and some novel chiral precursors for asymmetric synthesis.

引用

页码：4387 / 4395

页数：9

共 50 条

[31] Polymer supported zinc borohydride as a chemoselective reducing agent for reductive acetylation of aldehydes
Tamami, B
Goudarzian, N
Kiasat, AR
EUROPEAN POLYMER JOURNAL, 1997, 33 (06) : 977 - 978
[32] SODIUM-BOROHYDRIDE AND MANDELIC-ACID COMPLEX - A NEW REDUCING AGENT
NASIPURI, D
SARKAR, A
KONAR, SK
GHOSH, A
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1982, 21 (03): : 212 - 215
[33] SPECTROPHOTOMETRIC DETERMINATION OF ARSENIC WITH DIETHYLDITHIOCARBAMIC ACID SILVER SALT AND BOROHYDRIDE AS REDUCING AGENT
BASADREPAMPIN, M
ALVAREZDEVESA, A
BERMEJOMARTINEZ, F
BOLLAINRODRIGUEZ, MH
MICROCHEMICAL JOURNAL, 1978, 23 (03) : 360 - 365
[34] Polyvinylpyridine chloroaluminum borohydride as a new stable, and efficient reducing agent in organic synthesis
Tamami, B
Lakoraj, MM
Yeganeh, H
IRANIAN POLYMER JOURNAL, 1997, 6 (03) : 159 - 167
[35] Effect of borohydride as reducing agent on the structures and electrochemical properties of Pt/C catalyst
Ma, Hong-Chao
Xue, Xin-Zhong
Liao, Jian-Hui
Liu, Chang-Peng
Xing, Wei
APPLIED SURFACE SCIENCE, 2006, 252 (24) : 8593 - 8597
[36] Reduction of Benzonitriles via Osmium-Azavinylidene Intermediates Bearing Nucleophilic and Electrophilic Centers
Babon, Juan C.
Esteruelas, Miguel A.
Fernandez, Israel
Lopez, Ana M.
Onate, Enrique
INORGANIC CHEMISTRY, 2019, 58 (13) : 8673 - 8684
[37] PERCHLORATE-ANION AS A NUCLEOPHILIC AGENT IN THE FINAL STAGE OF ELECTROPHILIC ADDITION - PREPARATION OF STABLE PERCHLORATE
ZEFIROV, NS
KOZMIN, AS
KIRIN, VN
ZHDANKIN, VV
BODRIKOV, IV
ZHURNAL ORGANICHESKOI KHIMII, 1978, 14 (12): : 2615 - 2615
[38] REACTIONS OF THE 4A-HYDROPEROXIDE OF LIVER MICROSOMAL FLAVIN-CONTAINING MONOOXYGENASE WITH NUCLEOPHILIC AND ELECTROPHILIC SUBSTRATES
JONES, KC
BALLOU, DP
JOURNAL OF BIOLOGICAL CHEMISTRY, 1986, 261 (06) : 2553 - 2559
[39] A nonheme peroxo-diiron(iii) complex exhibiting both nucleophilic and electrophilic oxidation of organic substrates
Torok, Patrik
Unjaroen, Duenpen
Viktoria Csendes, Flora
Giorgi, Michel
Browne, Wesley R.
Kaizer, Jozsef
DALTON TRANSACTIONS, 2021, 50 (21) : 7181 - 7185
[40] REDUCTION OF INDIGO - SODIUM HYDROSULFITE AS A REDUCING AGENT
WILLIAMSON, KL
JOURNAL OF CHEMICAL EDUCATION, 1989, 66 (04) : 359 - 359

← 1 2 3 4 5 →