Zirconium borohydride - A versatile reducing agent for the reduction of electrophilic and nucleophilic substrates

被引：16

作者：

Narasimhan, S ^{[1
]}

Balakumar, R ^{[1
]}

机构：

[1] SPIC Sci Fdn, Ctr Agrochem Res, Madras 600032, Tamil Nadu, India

来源：

SYNTHETIC COMMUNICATIONS | 2000年 / 30卷 / 23期

关键词：

D O I：

10.1080/00397910008087061

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Zirconium borohydride, a potential reducing agent, reduces acids, esters, imines to the corresponding alcohols and secondary amines in good yield at room temperature within two hours. This facile reducing property was taken advantage off in the synthesis of pheromones and some novel chiral precursors for asymmetric synthesis.

引用

页码：4387 / 4395

页数：9

共 50 条

[21] BOROHYDRIDE EXCHANGE RESIN, A NEW REDUCING AGENT FOR REDUCTIVE AMINATION
YOON, NM
KIM, EG
SON, HS
CHOI, J
SYNTHETIC COMMUNICATIONS, 1993, 23 (11) : 1595 - 1599
[22] Identification of Nucleophilic and Electrophilic Binding Sites on Gold Surface-Enhanced Raman Substrates
Tripathi, Ashish
Emmons, Erik D.
Fountain, Augustus W., III
Christesen, Steven D.
Guicheteau, Jason A.
JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (41): : 23523 - 23528
[23] NMR evidence for the functionalization of non-planar corannulene surface by electrophilic and nucleophilic substrates
Zabula, Alexander V.
Dubceac, Cristina
Petrukhina, Marina A.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 241
[24] Potassium borohydride: Improved use as a reducing agent for organic and organometallic ketones
Darin, VA
Neto, AF
Borges, ADL
Miller, J
MAIN GROUP METAL CHEMISTRY, 1999, 22 (08): : 505 - 509
[25] REDUCTION OF SOME FUNCTIONAL-GROUPS WITH ZIRCONIUM TETRACHLORIDE SODIUM-BOROHYDRIDE
ITSUNO, S
SAKURAI, Y
ITO, K
SYNTHESIS-STUTTGART, 1988, (12): : 995 - 996
[26] Indium as a reducing agent: Reduction of oximes
Harrison, JR
Moody, CJ
Pitts, MR
SYNLETT, 2000, (11) : 1601 - 1602
[27] Benzytriphenylphosphonium borohydride (BTPPB) as a selective reducing agent for reduction of imines, enamines, and reductive amination of aldehydes with primary and secondry amines in methanol
Hajipour, AR
Mallakpour, SE
Najafi, AR
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2001, 170 : 197 - 203
[28] USE OF ZINC BOROHYDRIDE AS AN EFFICIENT AND HIGHLY SELECTIVE REDUCING AGENT - SELECTIVE REDUCTION OF KETONES AND CONJUGATED ALDEHYDES OVER CONJUGATED ENONES
SARKAR, DC
DAS, AR
RANU, BC
JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (22): : 5799 - 5801
[29] New chiral borohydride based reducing agent: Asymmetric reduction of 9-anthryl trifluoromethyl ketone and other carbonyl compounds
Maiti, DK
Bhattacharya, PK
SYNTHETIC COMMUNICATIONS, 1998, 28 (01) : 99 - 108
[30] New Chiral Borohydride Based Reducing Agent: Asymmetric Reduction of 9-Anthryl Trifluoromethyl Ketone and Other Carbonyl Compounds
Synth Commun, 1 (99):

← 1 2 3 4 5 →