Enantioselective aryl-aryl coupling facilitated by chiral binuclear gold complexes

被引：16

作者：

Himmelstrup, Jonas ^{[1
]}

Buendia, Mikkel B. ^{[1
]}

Sun, Xing-Wen ^{[2
]}

Kramer, Soren ^{[1
]}

机构：

[1] Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark

[2] Fudan Univ, Dept Chem, 220 Handan Rd, Shanghai 200433, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 86期

关键词：

C-H ACTIVATION; DUAL GOLD; PHOTOREDOX; ATROPISOMERS; CATALYSIS; ARENES; CONSTRUCTION; SELECTIVITY; SALTS; ACIDS;

D O I：

10.1039/c9cc07175j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we report stoichiometric investigations embodying the first highly enantioselective aryl-aryl coupling facilitated by a gold complex. With up to 91% ee, this is the first demonstration of a transmetalation and C(sp(2))-C(sp(2)) reductive elimination sequence with high enantioselectivity using a gold complex. The results offer a basis for development of enantioselective gold-catalyzed aryl-aryl coupling reactions.

引用

页码：12988 / 12991

页数：4

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