Effect of solvent polarity on the one-electron oxidation of cyclic nitroxyl radicals

被引：7
|
作者：
Manda, Sushma [1 ]
Nakanishi, Ikuo
Ohkubo, Kei
Kawashima, Tomonori
Matsumoto, Ken-ichiro
Ozawa, Toshihiko
Fukuzumi, Shunichi
Ikota, Nobuo
Anzai, Kazunori
机构：
[1] NIRS, Heavy Ion Radiobiol Res Grp, Res Ctr Charged Particle Therapy, Inage Ku, Chiba 2638555, Japan
[2] Osaka Univ, Dept Mat & Life Sci, Grad Sch Engn, SORST,JST, Suita, Osaka 5650871, Japan
[3] Shujitsu Univ, Sch Pharm, Okayama 7038516, Japan
[4] Tohoku Univ, NICHe, Aoba Ku, Sendai, Miyagi 9808579, Japan
来源：
CHEMISTRY LETTERS | 2007年 / 36卷 / 07期
关键词：
LIQUID/VAPOR INTERFACIAL REGION; VIVO ESR SPECTROSCOPY; OXOAMMONIUM CATIONS; KINETICS; SPECTRA; TEMPO; PROBE;
D O I：
10.1246/cl.2007.914
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The one-electron oxidation potentials of two cyclic nitroxyl radicals determined by the differential pulse voltammetry and cyclic voltammetry were found to shift negatively with the increased solvent polarity.
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页码：914 / 915
页数：2
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