Recent progress in the syntheses of mesoporous metal-organic framework materials

被引：144

作者：

Guan, Hong-Yu ^{[1
,2
]}

LeBlanc, Robert J. ^{[3
]}

Xie, Shu-Ya ^{[2
]}

Yue, Yanfeng ^{[3
]}

机构：

[1] Guangzhou Univ, Sch Chem & Chem Engn, Ctr Adv Analyt Sci, Guangzhou 510006, Guangdong, Peoples R China

[2] Northeast Normal Univ, Dept Chem, Changchun 130024, Jilin, Peoples R China

[3] Sul Ross State Univ, Dept Biol Geol & Phys Sci, Alpine, DC 79832 USA

来源：

COORDINATION CHEMISTRY REVIEWS | 2018年 / 369卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic framework; Mesopore fabrication; Hierarchical porous structure; Gas adsorption; TEMPLATE-FREE SYNTHESIS; MICROPOROUS MOF; ADSORPTION; CO2; CHEMISTRY; LIGAND; COMPLEXES; EFFICIENT; STRATEGY; CATALYST;

D O I：

10.1016/j.ccr.2018.05.001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metal-organic frameworks (MOFs), which are constructed from the assembly of metal ions or metal clusters with organic linkers, represent a new class of crystalline porous materials with potential applications in the fields of gas storage and separation, heterogeneous catalysis and chemical sensing. The development of reliable and reproducible methods to fabricate MOFs with high stability and mesopore characters remains a great challenge to meet many future applications for separation, large molecules adsorption, drug delivery and size-selective catalysis and so on. In this tutorial review, we are mainly focusing on the recent developments in the fabrication of hierarchically structured MOFs based on nanoscience techniques. (C) 2018 Elsevier B.V. All rights reserved.

引用

页码：76 / 90

页数：15

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