Synthesis and photophysical properties of peripherally metallated bis(dimethylamino)porphyrazines

被引：29
|
作者：
Sakellariou, EG
Montalban, AG
Meunier, HG
Ostler, RB
Rumbles, G
Barrett, AGM [1 ]
Hoffman, BM
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
[2] Assumption Coll, Dept Chem, Worcester, MA 01609 USA
[3] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2000年 / 136卷 / 03期
基金：
英国工程与自然科学研究理事会; 美国国家科学基金会;
关键词：
porphyrinoids; complexes; fluorescence; intersystem crossing;
D O I：
10.1016/S1010-6030(00)00343-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photophysics of the two novel solitaire porphyrazines 3 and 4 (obtained via coordination of PdCl2 and PtCl2 to the peripheral bis(dimethylamino) entity of the Zn-porphyrazine 1, respectively) have been examined using absorption, emission and transient absorption spectroscopy. While the free ligand 1 exhibits neither fluorescence nor triplet absorption, the peripherally metallated derivatives 3 and 4 display both fluorescence as well as intersystem crossing. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：185 / 187
页数：3
相关论文
共 50 条
  • [41] Synthesis and properties of 1-alkyl-4-(dimethylamino) pyridinium bis(trifluomethylsulfonyl)imides
    Stasiewicz, Monika
    Materna, Katarzyna
    Gras, Malgorzata
    Lota, Grzegorz
    CHEMIK, 2016, 70 (09): : 533 - 536
  • [42] Synthesis, structural and spectroscopic characterization, and photophysical and photochemical properties of peripherally tetratriazole-subsituted highly soluble metallophthalocyanines
    Bayrak, Riza
    Durmus, Mahmut
    Meydanal, Sevgi
    Sancak, Kemal
    Degirmencioglu, Ismail
    POLYHEDRON, 2012, 48 (01) : 1 - 8
  • [43] Non-peripherally alkylamino-substituted phthalocyanines: Synthesis, spectral, photophysical and acid-base properties
    Kociscakova, Lucia
    Senipek, Merve Ipek
    Zimcik, Petr
    Novakova, Veronika
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2019, 23 (4-5) : 427 - 436
  • [44] Synthesis and spectral properties of phenylene dendrimers based on porphyrazines
    Jaung, JY
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2004, 25 (10) : 1453 - 1454
  • [45] Synthesis and properties of unsymmetrical phenyl-substituted porphyrazines
    Kulinich, VP
    Shaposhnikov, GP
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2001, 71 (10) : 1632 - 1635
  • [46] PHOTOPHYSICAL PROPERTIES OF (DIMETHYLAMINO)ANTHRAQUINONES - RADIATIONLESS TRANSITIONS IN SOLVENT AND POLYELECTROLYTE MEDIA
    JONES, G
    FENG, ZM
    BERGMARK, WR
    JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (17): : 4511 - 4516
  • [47] Influence of functional groups on the photophysical properties of dimethylamino chalcones as laser dyes
    Ibnaouf, K. H.
    Elzupir, A. O.
    AlSalhi, M. S.
    Alaamer, Abdulaziz S.
    OPTICAL MATERIALS, 2018, 76 : 216 - 221
  • [48] Lanthanide(III) Bis(phthalocyaninato)-[60]Fullerene Dyads: Synthesis, Characterization, and Photophysical Properties
    Ballesteros, Beatriz
    de la Torre, Gema
    Shearer, Axel
    Hausmann, Anita
    Angeles Herranz, M.
    Guldi, Dirk M.
    Torres, Tomas
    CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (01) : 114 - 125
  • [49] New Ruthenium Bis(terpyridine) Methanofullerene and Pyrrolidinofullerene Complexes: Synthesis and Electrochemical and Photophysical Properties
    Barthelmes, Kevin
    Kuebel, Joachim
    Winter, Andreas
    Waechtler, Maria
    Friebe, Christian
    Dietzek, Benjamin
    Schubert, Ulrich S.
    INORGANIC CHEMISTRY, 2015, 54 (07) : 3159 - 3171
  • [50] Synthesis and photophysical properties of bis-cyclometalated iridium (III) dipyrrin complexes.
    Tamayo, AB
    Ly, J
    Ma, BW
    Djurovich, PI
    Thompson, ME
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 229 : U1106 - U1107
12345