Synthesis and photophysical properties of peripherally metallated bis(dimethylamino)porphyrazines

被引：29
|
作者：
Sakellariou, EG
Montalban, AG
Meunier, HG
Ostler, RB
Rumbles, G
Barrett, AGM [1 ]
Hoffman, BM
机构：
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England
[2] Assumption Coll, Dept Chem, Worcester, MA 01609 USA
[3] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
来源：
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2000年 / 136卷 / 03期
基金：
英国工程与自然科学研究理事会; 美国国家科学基金会;
关键词：
porphyrinoids; complexes; fluorescence; intersystem crossing;
D O I：
10.1016/S1010-6030(00)00343-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The photophysics of the two novel solitaire porphyrazines 3 and 4 (obtained via coordination of PdCl2 and PtCl2 to the peripheral bis(dimethylamino) entity of the Zn-porphyrazine 1, respectively) have been examined using absorption, emission and transient absorption spectroscopy. While the free ligand 1 exhibits neither fluorescence nor triplet absorption, the peripherally metallated derivatives 3 and 4 display both fluorescence as well as intersystem crossing. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：185 / 187
页数：3
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