Synthesis, characterisation and thermal behaviour of solid state compounds of 4-methylbenzylidenepyruvate with heavier trivalent lanthanides and yttrium(III)

被引：0
|
作者：
Marques, RN [1 ]
Melios, CB [1 ]
Ionashiro, M [1 ]
机构：
[1] UNESP, Inst Quim, BR-14801970 Araraquera, SP, Brazil
来源：
THERMOCHIMICA ACTA | 2003年 / 395卷 / 1-2期
关键词：
heavier trivalent lanthanides; yttrium(III); 4-methylbenzylidenepyruvate; complexes; characterization; thermal behaviour;
D O I：
暂无
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Solid state Ln-4-Me-BP compounds, where Ln stands for heavier trivalent lanthanides (gadolinium to lutetium) and yttrium(III) and 4-Me-BP is 4-methylbenzylidenepyruvate (CH3-C6H4-CH=CH-COCOO-), have been synthesized. Elemental analysis, complexometry, X-ray powder diffractometry, infrared spectroscopy and simultaneous thermogravimetry-differential thermal analysis (TG-DTA), have been used to characterise and to study the thermal behaviour of these compounds. The results provided information concerning the stoichiometry, crystallinity, ligand's denticity, thermal stability and thermal decomposition. (C) 2002 Elsevier Science B.V All rights reserved.
引用
收藏
页码：145 / 150
页数：6
相关论文
共 50 条
  • [31] Synthesis, characterization and thermal behaviour of solid-state compounds of europium(III) and gadolinium(III) 3-methoxybenzoate
    Dametto, Patricia R.
    Ambrozini, Beatriz
    Siqueira, Adriano B.
    Carvalho, Claudio T.
    Ionashiro, Massao
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 97 (02) : 765 - 768
  • [32] Solid-state compounds of 4-chlorobenzylidenepyruvate with lanthanides preparation and thermal studies
    Fernandes, N.S.
    Carvalho Filho, M.A.S.
    Melios, C.B.
    Ionashiro, M.
    Journal of Thermal Analysis and Calorimetry, 2000, 59 (03) : 663 - 668
  • [33] Synthesis, characterization and thermal behaviour of solid-state compounds of europium(III) and gadolinium(III) 3-methoxybenzoate
    Patrícia R. Dametto
    Beatriz Ambrozini
    Adriano B. Siqueira
    Cláudio T. Carvalho
    Massao Ionashiro
    Journal of Thermal Analysis and Calorimetry, 2009, 97 : 765 - 768
  • [34] Synthesis, characterization and thermal behavior of solid state of some mefenamate of trivalent lanthanides (La, Ce, Pr and Nd)
    Francisco X. Campos
    André L. C. S. Nascimento
    Tiago A. D. Colman
    Diogo A. Gálico
    Oswaldo Treu-Filho
    Flávio J. Caires
    Adriano B. Siqueira
    Massao Ionashiro
    Journal of Thermal Analysis and Calorimetry, 2016, 123 : 91 - 103
  • [35] Synthesis, characterization and thermal behavior of solid state of some mefenamate of trivalent lanthanides (La, Ce, Pr and Nd)
    Campos, Francisco X.
    Nascimento, Andre L. C. S.
    Colman, Tiago A. D.
    Galico, Diogo A.
    Treu-Filho, Oswaldo
    Caires, Flavio J.
    Siqueira, Adriano B.
    Ionashiro, Massao
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2016, 123 (01) : 91 - 103
  • [36] Synthesis, characterization and thermal behavior of solid state compounds of heavy trivalent lanthanide succinates
    Lima, L. S.
    Caires, F. J.
    Gigante, A. C.
    Gomes, D. J. C.
    Siqueira, A. B.
    Carvalho, C. T.
    Ionashiro, M.
    THERMOCHIMICA ACTA, 2013, 557 : 31 - 36
  • [37] 4-Dimethylaminocinnamylidenepyruvic acid: Synthesis, characterization and complexation with trivalent lanthanides, yttrium(III), scandium(III), thorium(IV) and uranium(VI) in aqueous solution
    Pereira, N.C.S.
    Melios, C.B.
    Marques, R.N.
    Siqueira, O.S.
    de Moraes, M.
    Molina, M.
    Ionashiro, M.
    Journal of Alloys and Compounds, 1997, 249 (1 -2 pt 1): : 94 - 98
  • [38] 4-Dimethylaminocinnamylidenepyruvic acid: Synthesis, characterization and complexation with trivalent lanthanides, yttrium(III), scandium(III), thorium(IV) and uranium(VI) in aqueous solution
    Pereira, NCS
    Melios, CB
    Marques, RN
    Siqueira, OS
    deMoraes, M
    Molina, M
    Ionashiro, M
    JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 249 (1-2) : 94 - 98
  • [39] Solid-state compounds of 4-chloro-benzylidenepyruvate with lanthanides. Preparation and thermal studies
    Fernandes, NS
    Carvalho, MAS
    Melios, CB
    Ionashiro, M
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2000, 59 (03): : 663 - 668
  • [40] Solid-state Compounds of 4-chloro-benzylidenepyruvate With Lanthanides. Preparation and thermal studies
    N. S. Fernandes
    M. A. S. Carvalho Filho
    C. B. Melios
    M. Ionashiro
    Journal of Thermal Analysis and Calorimetry, 2000, 59 : 663 - 668
12345