Effects of the cation size and shape on the stability of clathrate hydrates in the series of H2O-(i-C5H11)4-k(C4H9)kNBr (k=0, 1, 2, 3, 4) systems

被引：0

作者：

Aladko, LS ^{[1
]}

Dyadin, YA ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2004年 / 49卷 / 10期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The i-AmBu3NBr-H2O phase diagram is studied in the crystallization region of clathrate hydrates. Four polyhydrates with hydration numbers of 38 (mp = 13.8degreesC), 32 (16.1degreesC), 26 (17.0degreesC), and 24 (17.3degreesC) are found. Crystals of the most stable congruently melting compound are isolated, and their composition and melting temperature are determined. The influence of the cation size and shape on clathrate formation in the H2O-(i-C5H11)(4- k)(C4H9)(k)NBr (k = 0, 1, 2, 3, 4) series is considered.

引用

页码：1596 / 1600

页数：5

共 50 条

[11] SOLUBILITY POLYTHERM IN TERNARY SYSTEM HNO3-H2O-(C4H9O)PO(C4H9)2
NIKOLAEV, AV
DYADIN, YA
YAKOVLEV, II
DOKLADY AKADEMII NAUK SSSR, 1965, 160 (04): : 841 - &
[12] 5-COMPOUND SYSTEM UO2(NO3)2-(C4H9)2PO(C4H9O) - H2O - HNO3 - CCL4 WITH A CONSTANT RELATION OF (C4H9)2PO(C4H9O) TO CCL4 IN STRATIFICATION REGION
NIKOLAEV, AV
MIRONOVA, ZN
DIADIN, IA
IAKOVLEV, II
DOKLADY AKADEMII NAUK SSSR, 1963, 153 (01): : 118 - &
[13] Syntheses of Monomeric Bis(Dialkoxyorganylsiloxy)Dibutylstannanes Bu2Sn[OSi(R′) (OR)2]2 (R=C3H7, C4H9, i−C4H9, C5H11; R′=Vi, Ph)
Alexander V. Alikovskii
Victoria V. Vasileva
Elena T. Dan’ko
Svetlana G. Krasitskaya
Mikhail I. Balanov
Silicon, 2015, 7 : 229 - 234
[14] CLATHRATE FORMATION UNDER PRESSURE IN THE H2O-CH3(C4H9)2PO SYSTEM
ALADKO, EY
DYADIN, YA
IZVESTIYA SIBIRSKOGO OTDELENIYA AKADEMII NAUK SSSR SERIYA KHIMICHESKIKH NAUK, 1982, (01): : 77 - 80
[15] The cubic superstructure-I of tetrabutylammonium fluoride (C4H9)4NF•29.7H2O clathrate hydrate
Komarov, V. Yu.
Rodionova, T. V.
Terekhova, I. S.
Kuratieva, N. V.
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2007, 59 (1-2) : 11 - 15
[16] The Cubic Superstructure-I of Tetrabutylammonium Fluoride (C4H9)4NF·29.7H2O Clathrate Hydrate
V. Yu. Komarov
T. V. Rodionova
I. S. Terekhova
N. V. Kuratieva
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2007, 59 : 11 - 15
[17] COMPLEXES OF ANTIMONY(III) .1. POLAROGRAPHIC STUDIES ON COMPLEX-FORMATION IN SYSTEMS - SB(CLO4)3-L-H2O (L=CHO2-, C2H3O2-, C3H5O2-, C3H5O3-, C3H2O4--, C4H4O4--, C5H6O4--, C4H2O4--, C4H4O5-, AND C4H4O6--)
WOJTAS, R
ROCZNIKI CHEMII, 1975, 49 (7-8): : 1231 - 1237
[18] REACTIONS OF POLYOXOMOLYBDATES WITH OXIMES - THE CRYSTAL AND MOLECULAR-STRUCTURES OF [(C4H9)4N]2[MO2O5(C6H4(O)CHNO)2].CH2CL2 AND [(C4H9)4N]2[MO2O5(C6H5CH(O)C(NO)C6H5)2]
LIU, SC
ZHU, HZ
ZUBIETA, J
POLYHEDRON, 1989, 8 (20) : 2473 - 2480
[19] STUDY OF THE BINARY-SYSTEMS H2O-(NH4)3CR(C2O4)3 AND H2O-(NH4)3FE(C2O4)3
MERRACHI, E
COHENADAD, R
CHASSAGNEUX, F
PARIS, J
MENTZEN, BF
BOUIX, J
REVUE DE CHIMIE MINERALE, 1986, 23 (02): : 191 - 200
[20] CRYSTAL-STRUCTURES OF TETRABUTYLAMMONIUM DICHLOROCUPRATE(I) AND TETRABUTYLAMMONIUM DIBROMOCUPRATE(I), [N(C4H9)4][CUCL2] AND [N(C4H9)4][CUBR2]
ASPLUND, M
JAGNER, S
NILSSON, M
ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1983, 37 (01): : 57 - 62

← 1 2 3 4 5 →