Synthesis of hollow Prussian blue cubes as an electrocatalyst for the reduction of hydrogen peroxide

被引:10
|
作者
Sheng, Qinglin [1 ]
Zhang, Dan [1 ]
Shen, Yu [1 ]
Zheng, Jianbin [1 ]
机构
[1] Northwest Univ Xian, Shaanxi Prov Key Lab Electroanalyt Chem, Inst Analyt Sci, Xian 710069, Peoples R China
基金
中国国家自然科学基金;
关键词
Prussian blue; hollow structure; hydrogen peroxide; sensor; non-enzyme; electrocatalyst; METAL-ORGANIC-FRAMEWORKS; H2O2; DETECTION; ELECTROCHEMICAL DETECTION; MODIFIED ELECTRODES; CARBON NANOTUBES; IONIC LIQUID; GLUCOSE; SENSOR; PERFORMANCE; BIOSENSORS;
D O I
10.1007/s11706-017-0382-z
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A cubic Prussian blue (PB) with the hollow interior was successfully synthesized by direct dissociation followed by a controlled self-etching process. The etching process also made hollow Prussian blue (HPB) a porous structure. SEM, TEM and XRD were employed to confirm the structure and morphology of the prepared materials. Then HPB and chitosan (CS) were deposited on a glassy carbon electrode (GCE), used to determine H2O2. The amperometric performance of HPB/CS/GCE was investigated. It was found that the special structure of HPB exhibits enhanced performance in the H2O2 sensing.
引用
收藏
页码:147 / 154
页数:8
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