Kinetics and mechanism of the ruthenium(III) catalyzed oxidation of propane-1,3-diol by alkaline hexacyanoferrate(III)

被引：3
|
作者：
Mucientes, AE
Poblete, FJ
Santiago, F
Casado, J
机构：
[1] Univ Castilla La Mancha, Fac Quim, Dept Quim Fis, E-13071 Ciudad Real, Spain
[2] Univ Salamanca, Fac Quim, Dept Quim Fis, E-37008 Salamanca, Spain
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1997年 / 62卷 / 02期
关键词：
kinetics; catalytic oxidation; alcohols; Ru(III);
D O I：
10.1007/BF02475466
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of oxidation of propane-1,3-diol by alkaline hexacyanoferrate (III) catalyzed by ruthenium trichloride has been studied spectrophotometrically. A reaction mechanism involving the formation of an intermediate complex between the substrate and the catalyst is proposed. In the rate-determining step this complex is attacked by hexacyanoferrate (III) forming a free radical which is further oxidized.
引用
收藏
页码：293 / 297
页数：5
相关论文
共 50 条
  • [41] Synthesis of quinolines by iron-catalyzed reaction of anilines with propane-1,3-diol
    R. I. Khusnutdinov
    A. R. Bayguzina
    R. I. Aminov
    Russian Journal of General Chemistry, 2015, 85 : 2725 - 2727
  • [42] KINETICS AND MECHANISM OF ALKALINE HEXACYANOFERRATE(III) OXIDATION OF LEVULINIC ACID
    SINGH, B
    SINGH, BB
    SINGH, S
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1980, 57 (06) : 662 - 663
  • [43] KINETICS AND MECHANISM OF OXIDATION OF PHENACYL BROMIDE BY ALKALINE HEXACYANOFERRATE(III)
    PILLAY, MK
    KHAN, SMMN
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 1993, 70 (03) : 209 - 210
  • [44] KINETICS AND MECHANISM OF ALKALINE POTASSIUM HEXACYANOFERRATE(III) OXIDATION OF MORPHOLINE
    SINGH, B
    SINGH, S
    ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-LEIPZIG, 1981, 262 (05): : 913 - 918
  • [45] Synthesis of Quinolines by Iron-Catalyzed Reaction of Anilines with Propane-1,3-diol
    Khusnutdinov, R. I.
    Bayguzina, A. R.
    Aminov, R. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2015, 85 (12) : 2725 - 2727
  • [46] KINETICS AND MECHANISM OF OXIDATION OF ALIPHATIC-ALCOHOLS AND DIOLS BY ALKALINE HEXACYANOFERRATE(III) CATALYZED BY RU(III) CHLORIDE
    RADHAKRISHNAMURTI, PS
    SAHU, B
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1979, 17 (01): : 95 - 97
  • [47] Effect of Gold Deposition on the Activity of Palladium Electrode for Propane-1,3-diol Oxidation
    Jin, Changchun
    Zhang, Jingjing
    Huo, Qisheng
    Dong, Rulin
    CHEMISTRY LETTERS, 2015, 44 (02) : 194 - 196
  • [48] Kinetics of iridium(III) catalysed oxidation of butane 1:4-diol with alkaline Hexacyanoferrate(III)
    Seth, SK
    Goel, A
    Verma, GR
    Singh, HS
    ASIAN JOURNAL OF CHEMISTRY, 2001, 13 (02) : 505 - 508
  • [49] Ruthenium(III) catalyzed oxidation of hexacyanoferrate(II) by periodate in aqueous alkaline medium
    Hiremath, GA
    Timmanagoudar, PL
    Nandibewoor, ST
    REACTION KINETICS AND CATALYSIS LETTERS, 1998, 63 (02): : 403 - 408
  • [50] Different behaviors of PdAu/C catalysts in electrooxidation of propane-1,3-diol and propane-1,2-diol
    Changchun Jin
    Zhongyu Wang
    Qisheng Huo
    Rulin Dong
    Ionics, 2015, 21 : 841 - 847
12345