Kinetics and mechanism of the ruthenium(III) catalyzed oxidation of propane-1,3-diol by alkaline hexacyanoferrate(III)

被引：3

作者：

Mucientes, AE

Poblete, FJ

Santiago, F

Casado, J

机构：

[1] Univ Castilla La Mancha, Fac Quim, Dept Quim Fis, E-13071 Ciudad Real, Spain

[2] Univ Salamanca, Fac Quim, Dept Quim Fis, E-37008 Salamanca, Spain

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1997年 / 62卷 / 02期

关键词：

kinetics; catalytic oxidation; alcohols; Ru(III);

D O I：

10.1007/BF02475466

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetics of oxidation of propane-1,3-diol by alkaline hexacyanoferrate (III) catalyzed by ruthenium trichloride has been studied spectrophotometrically. A reaction mechanism involving the formation of an intermediate complex between the substrate and the catalyst is proposed. In the rate-determining step this complex is attacked by hexacyanoferrate (III) forming a free radical which is further oxidized.

引用

页码：293 / 297

页数：5

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