Synthesis and crystal structure of new dinitro derivatives of sesquiterpene lactone achillin

被引：0
|
作者：
Mynzhasarovich, AS
Bagdatovna, RB
Tabylovich, KA
Zareen, S
Choudhary, MI
Atta-ur-Rahman
机构：
[1] Minist Educ & Sci, Inst Phytochem, Karaganda 470032, Kazakhstan
[2] Univ Karachi, HEJ Res Inst Chem, Int Ctr Chem Sci, Karachi 75270, Pakistan
来源：
HETEROCYCLES | 2003年 / 60卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An unexpected dinitro derivative (2) of sesquiterpene lactone achillin (1), isolated from the aerial part of Achillea micrantha Wild., was formed when this compound was exposed to gaseous NOCl in CHCl3. This derivative was transformed into dinitrocarbonic acid (3) in pyridine in 30 minutes and in quantitative yield. The structures of these compounds were unambiguously determined by single-crystal X-Ray diffraction analysis.
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页码：1053 / 1063
页数：11
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