Synthesis and crystal structure of new dinitro derivatives of sesquiterpene lactone achillin

被引：0
|
作者：
Mynzhasarovich, AS
Bagdatovna, RB
Tabylovich, KA
Zareen, S
Choudhary, MI
Atta-ur-Rahman
机构：
[1] Minist Educ & Sci, Inst Phytochem, Karaganda 470032, Kazakhstan
[2] Univ Karachi, HEJ Res Inst Chem, Int Ctr Chem Sci, Karachi 75270, Pakistan
来源：
HETEROCYCLES | 2003年 / 60卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An unexpected dinitro derivative (2) of sesquiterpene lactone achillin (1), isolated from the aerial part of Achillea micrantha Wild., was formed when this compound was exposed to gaseous NOCl in CHCl3. This derivative was transformed into dinitrocarbonic acid (3) in pyridine in 30 minutes and in quantitative yield. The structures of these compounds were unambiguously determined by single-crystal X-Ray diffraction analysis.
引用
收藏
页码：1053 / 1063
页数：11
相关论文
共 50 条
  • [21] DIMERIC SESQUITERPENE LACTONE - STRUCTURE OF ISOABSINTHIN ACID ISOMERIZATION OF ABSINTHIN DERIVATIVES
    BEAUHAIRE, J
    FOURREY, JL
    LALLEMAND, JY
    VUILHORGNE, M
    TETRAHEDRON LETTERS, 1981, 22 (24) : 2269 - 2272
  • [22] Structure of the sesquiterpene lactone artapshinin
    Safarova A.G.
    Serkerov S.V.
    Aleskerova A.N.
    Chemistry of Natural Compounds, 1997, 33 (6) : 655 - 657
  • [23] STRUCTURE OF SESQUITERPENE LACTONE ELEGINE
    SHAMYANOV, ID
    MALLABAJEV, A
    SIDYAKIN, GP
    KHIMIYA PRIRODNYKH SOEDINENII, 1978, (04): : 442 - 445
  • [24] STRUCTURE OF RATIBINOLIDE, A SESQUITERPENE LACTONE
    SORIANOGARCIA, M
    IRIBE, RV
    MATA, R
    ROJAS, A
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1990, 46 : 1966 - 1968
  • [25] Structure of Sesquiterpene lactone (Artapshinin)
    Safarova, AG
    Serkerov, SV
    Aleskerova, AN
    KHIMIYA PRIRODNYKH SOEDINENII, 1997, (06): : 837 - 840
  • [26] SESQUITERPENE LACTONE TOTAL SYNTHESIS
    GRIECO, PA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1977, 173 (MAR20): : 51 - 51
  • [27] First synthesis of dialkyl phosphonate derivatives of sesquiterpene α-methylene-γ-lactone
    R. I. Jalmahanbetova
    B. B. Rakhimova
    V. A. Raldugin
    I. Yu. Bagryanskaya
    Yu. V. Gatilov
    M. M. Shakirov
    A. T. Kulyjasov
    S. M. Adekenov
    G. A. Tolstikov
    Russian Chemical Bulletin, 2003, 52 : 748 - 751
  • [28] STRUCTURE OF SESQUITERPENE LACTONE LAURENOBIOLIDE
    TADA, H
    TAKEDA, K
    JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (21): : 1391 - &
  • [29] X-RAY CRYSTAL-STRUCTURE OF THE SESQUITERPENE LACTONE SCORPIOIDINE
    DREW, MGB
    HITCHMAN, SP
    MANN, J
    LOPES, JLC
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (17) : 802 - 803
  • [30] CRYSTAL AND MOLECULAR-STRUCTURE OF ZOAPATANOLIDE-B, A SESQUITERPENE LACTONE
    COWE, HJ
    COX, PJ
    HOWIE, RA
    JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1990, 20 (06): : 571 - 576
12345