Chlorido(η5-cyclopentadienyl)bis-(dimethylamido)titanium, [TiCl(η5-C5H5)(NMe2)2]

被引：2

作者：

Chapin, Brette M. ^{[1
]}

Hughs, Lauren D. ^{[1
]}

Golen, James A. ^{[2
]}

Rheingold, Arnold L. ^{[3
]}

Johnson, Adam R. ^{[1
]}

机构：

[1] Harvey Mudd Coll, Dept Chem, Claremont, CA 91711 USA

[2] Univ Massachusetts, Dept Chem, N Dartmouth, MA 02747 USA

[3] Univ Calif San Diego, Dept Chem, La Jolla, CA 92093 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2010年 / 66卷

基金：

美国国家科学基金会;

关键词：

COMPLEXES; TITANIUM; TI;

D O I：

10.1107/S0108270110023176

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, [Ti(C5H5)(C2H6N)(2)Cl], exhibits two nearly planar dimethylamide groups oriented approximately perpendicular to each other. The Ti -> cyclopentadienyl centroid vector lies nearly in the plane of one of the dimethylamide groups. Long-range contacts between Ti-Cl and cyclopentadienyl H-C groups give rise to geometric ordering in the extended solid.

引用

页码：M191 / M193

页数：3

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