Chlorido(η5-cyclopentadienyl)bis-(dimethylamido)titanium, [TiCl(η5-C5H5)(NMe2)2]

被引：2
|
作者：
Chapin, Brette M. [1 ]
Hughs, Lauren D. [1 ]
Golen, James A. [2 ]
Rheingold, Arnold L. [3 ]
Johnson, Adam R. [1 ]
机构：
[1] Harvey Mudd Coll, Dept Chem, Claremont, CA 91711 USA
[2] Univ Massachusetts, Dept Chem, N Dartmouth, MA 02747 USA
[3] Univ Calif San Diego, Dept Chem, La Jolla, CA 92093 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2010年 / 66卷
基金：
美国国家科学基金会;
关键词：
COMPLEXES; TITANIUM; TI;
D O I：
10.1107/S0108270110023176
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title complex, [Ti(C5H5)(C2H6N)(2)Cl], exhibits two nearly planar dimethylamide groups oriented approximately perpendicular to each other. The Ti -> cyclopentadienyl centroid vector lies nearly in the plane of one of the dimethylamide groups. Long-range contacts between Ti-Cl and cyclopentadienyl H-C groups give rise to geometric ordering in the extended solid.
引用
收藏
页码：M191 / M193
页数：3
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