{3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)

被引：6
|
作者：
Assey, Gervas E. [1 ]
Butcher, Ray J. [1 ]
Gultneh, Yilma [1 ]
机构：
[1] Howard Univ, Dept Chem, Washington, DC 20059 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
SCHIFF-BASE COMPLEXES; X-RAY; NICKEL(II); SUBSTITUENTS; OXIDATION; SALEN;
D O I：
10.1107/S1600536810016041
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title square-planar nickel complex, [Ni(C(20)H(22)N(2)O(6))],has Ni-N and Ni-O bond lengths of 1.8448 (14)/1.8478 (14) and 1.8536 (12)/1.8520 (12) angstrom. There is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 11.11 (5)degrees]. All the atoms of the methoxy substitutents are in the plane of the ring to which they are attached except for one which deviates slightly [0.365 (3) angstrom]. In the crystal, weak C-H center dot center dot center dot O intermolecular interactions connect the molecules.
引用
收藏
页码：M620 / U273
页数：11
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