Electron doping of single-walled carbon nanotubes using pyridine-boryl radicals

被引：4

作者：

Tanaka, Naoki ^{[1
,2
]}

Hamasuna, Aoi ^{[1
]}

Uchida, Takuto ^{[1
]}

Yamaguchi, Ryohei ^{[1
]}

Ishii, Taiki ^{[1
]}

Staylkov, Aleksandar ^{[2
]}

Fujigaya, Tsuyohiko ^{[1
,2
,3
]}

机构：

[1] Kyushu Univ, Dept Appl Chem, Grad Sch Engn, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan

[2] Kyushu Univ, Int Inst Carbon Neutral Energy Res WPI I2CNER, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan

[3] Kyushu Univ, Ctr Mol Syst CMS, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 49期

基金：

日本学术振兴会; 日本科学技术振兴机构;

关键词：

LEWIS-BASES; REACTIVITY; BORYLLITHIUM; CONVERSION;

D O I：

10.1039/d1cc01354h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyridine-boryl (py-boryl) radicals serve as efficient electron-doping reagents for single-walled carbon nanotubes (SWCNTs). The doping mechanism comprises electron transfer from the py-boryl radical to the SWCNT. The formation of a stable py-boryl cation is essential for efficient doping; the captodative effect of the py-boryl cation is important to this process.

引用

页码：6019 / 6022

页数：4

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