New syntheses and crystal structures of bis(fluorophenyl) mercury, Hg(Rf)2 (Rf = C6F5, 2,3,4,6-F4C6H, 2,3,5,6-F4C6H, 2,4,6-F3C6H2, 2,6-F2C6H3)

被引：6
|
作者：
Naumann, D [1 ]
Schulz, F [1 ]
机构：
[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 01期
关键词：
mercury; fluorophenyl compounds; crystal structures;
D O I：
10.1002/zaac.200400244
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Bis(fluorophenyl) mercury compounds, Hg(R-f)(2) (R-f = C6F5, C6HF4, C6H2F3, C6H3F2), are prepared in good yields by the reactions of HgF2 with Me3SiRf. The crystal structures of Hg(2,3,4,6-F4C6H)(2) (monoclinic, P2(1)/n), Hg(2,3,5,6-F4C6H)(2) (monoclinic, C2/m), Hg(2,4,6-F3C6H2)(2) (monoclinic, P2(1)/c) and Hg(2,6-F2C6H3)(2) (triclinic, P (1) over bar) are described.
引用
收藏
页码：122 / 125
页数：4
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