REACTION OF (C6F5)(2)HGEGEH(C6F5)(2) WITH TRIETHYLBISMUTH - MOLECULAR-STRUCTURE OF [(C6F5)(2)GE]4BI2

被引：2

作者：

PANKRATOV, LV ^{[1
]}

ZAKHAROV, LN ^{[1
]}

BOCHKOVA, RI ^{[1
]}

FUKIN, GK ^{[1
]}

STRUCHKOV, YT ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,AN NESMEYANOV ORGANOELEMENT CPDS INST,MOSCOW 117813,RUSSIA

来源：

RUSSIAN CHEMICAL BULLETIN | 1994年 / 43卷 / 05期

关键词：

POLYNUCLEAR COMPOUNDS; SYNTHESIS; PENTAFLUOROPHENYL GROUPS; GERMYLBISMUTH COMPLEX; X-RAY STRUCTURAL ANALYSIS;

D O I：

10.1007/BF00717357

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of (C6F5)(2)HGeGeH(C6F5) with triethylbismuth affords a new polynuclear germylbismuth derivative, [(C6F5)(2)Ge]Bi-4(2) (1) The metal framework of molecule 1 has the form of a gable roof built by two central Bi atoms and four peripheral Ge atoms with covalent Bi-Bi bonds [3.045(3) Angstrom], Bi-Ge [2.724(5)-2.755(5) Angstrom] and Ge-Ge [2.444(6), 2.465(6) Angstrom].

引用

页码：867 / 870

页数：4

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