Polymerization of acrylates by atom transfer radical polymerization. Homopolymerization of glycidyl acrylate

被引：40
|
作者：
Matyjaszewski, K [1 ]
Coca, S [1 ]
Jasieczek, CB [1 ]
机构：
[1] Carnegie Mellon Univ, Mellon Inst, Dept Chem, Pittsburgh, PA 15213 USA
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 1997年 / 198卷 / 12期
关键词：
D O I：
10.1002/macp.1997.021981219
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Atom transfer radical polymerization (ATRP) was applied to the homopolymerization of glycidyl acrylate (GA). This functionalized monomer can be polymerized to high conversions and high molecular weights using halogenated initiators and CuBr/4,4'-bis(5-nonyl)-2,2'-bipyridine (dNbipy) as the catalyst. The polymerizations exhibit first order kinetics and molecular weights increase linearly with conversion. The (M) over bar(n) of the products is controlled by the ratio Delta[M](0)/[I](0). The polymers obtained showed narrow molecular weight distributions, (M) over bar(w)/(M) over bar(n) = 1.25.
引用
收藏
页码：4011 / 4017
页数：7
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