Polymerization of acrylates by atom transfer radical polymerization. Homopolymerization of glycidyl acrylate

被引：40
|
作者：
Matyjaszewski, K [1 ]
Coca, S [1 ]
Jasieczek, CB [1 ]
机构：
[1] Carnegie Mellon Univ, Mellon Inst, Dept Chem, Pittsburgh, PA 15213 USA
来源：
MACROMOLECULAR CHEMISTRY AND PHYSICS | 1997年 / 198卷 / 12期
关键词：
D O I：
10.1002/macp.1997.021981219
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Atom transfer radical polymerization (ATRP) was applied to the homopolymerization of glycidyl acrylate (GA). This functionalized monomer can be polymerized to high conversions and high molecular weights using halogenated initiators and CuBr/4,4'-bis(5-nonyl)-2,2'-bipyridine (dNbipy) as the catalyst. The polymerizations exhibit first order kinetics and molecular weights increase linearly with conversion. The (M) over bar(n) of the products is controlled by the ratio Delta[M](0)/[I](0). The polymers obtained showed narrow molecular weight distributions, (M) over bar(w)/(M) over bar(n) = 1.25.
引用
收藏
页码：4011 / 4017
页数：7
相关论文
共 50 条
  • [21] Effect of solvents on atom-transfer radical polymerization.
    Ziegler, MJ
    Paik, HJ
    Davis, KA
    Gaynor, SG
    Matyjaszewski, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U542 - U542
  • [22] Preparation of macrodiols by atom-transfer radical polymerization.
    Shim, AK
    Coessens, V
    Pintauer, T
    Matyjaszewski, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U545 - U545
  • [23] Understanding the catalytic systems for atom transfer radical polymerization.
    Matyjaszewski, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U297 - U297
  • [24] Polyacrylonitrile with low polydispersities by atom transfer radical polymerization.
    Jo, SM
    Paik, HJ
    Matyjaszewski, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 325 - POLY
  • [25] Graft copolymers by atom-transfer radical polymerization.
    Matyjaszewski, K
    Beers, KL
    Gaynor, SG
    Coca, S
    Paik, HJ
    Teodorescu, M
    Miller, PJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U495 - U496
  • [26] Polymerization of sodium 4-styrenesulfonate via atom transfer radical polymerization.
    Iddon, PD
    Robinson, KL
    Armes, SP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 228 : U352 - U352
  • [27] Gradient copolymers of styrene and n-butyl acrylate through atom transfer radical polymerization.
    Arehart, SV
    Greszta, D
    Matyjaszewski, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 329 - POLY
  • [28] Atom-transfer radical polymerization of acrylates in an ionic liquid
    Biedron, T
    Kubisa, P
    MACROMOLECULAR RAPID COMMUNICATIONS, 2001, 22 (15) : 1237 - 1242
  • [29] Controlled/"living" radical polymerization. Atom transfer radical polymerization using multidentate amine ligands
    Xia, JH
    Matyjaszewski, K
    MACROMOLECULES, 1997, 30 (25) : 7697 - 7700
  • [30] Atom transfer radical polymerization of glycidyl methacrylate:: A functional monomer
    Cañamero, PF
    de la Fuente, JL
    Madruga, EL
    Fernández-García, M
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2004, 205 (16) : 2221 - 2228
12345