Structural characterization of a zinc(II) complex of a tris(oxime)amine ligand

被引：10
|
作者：
Goldcamp, MJ [1 ]
Bauer, JAK [1 ]
Baldwin, MJ [1 ]
机构：
[1] Univ Cincinnati, Dept Chem, Cincinnati, OH 45221 USA
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2005年 / 35卷 / 01期
关键词：
diacetato-(tris(1-propan-2-onyl oxime)amine)zinc(II); diacetato-(tris(2-hydroxyliminopropyl)amine)zinc(II); X-ray crystal structure; synthesis;
D O I：
10.1007/s10870-005-1158-3
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The ligand tris(1-propan-2-onyl oxime)amine (TRISOXH3) binds to zinc(II) acetate as a tridentate N-3 donor, with a third oxime group remaining unbound and extending into the crystal lattice. The crystal structure shows a distorted trigonal bipyramidal geometry around the zinc center. An intramolecular hydrogen bonding interaction between a coordinated oxime donor and an oxygen of a bound acetate is observed. This structure is similar to that of a previously reported zinc(II) complex of a related bis(oxime)amine ligand. However, the structure of Zn(TRISOXH3)(OAc)(2) is different in ligand coordination mode and metal coordination number from those of the previously reported complexes Ni(TRISOXH3)Cl-2 or [Ni(TRISOXH3)(NO3)(H2O)]NO3.
引用
收藏
页码：77 / 83
页数：7
相关论文
共 50 条
  • [41] Synthesis, crystal structure and cyclic voltammetry of a copper(II) complex with tripod ligand tris(2-benzimidazolylmethyl)amine
    Su, ZX
    Wan, YQ
    Wu, HL
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2005, 35 (07) : 553 - 558
  • [42] Synthesis, structure and biological activity of Zn(II) complex with tris(benzimidazol-2-yl-methyl)amine ligand
    Liu, XL
    Ru, Z
    Liu, XH
    Yue, JJ
    Yin, YX
    Yun, S
    Ming, S
    CHINESE JOURNAL OF CHEMISTRY, 2004, 22 (01) : 75 - 79
  • [43] Synthesis,Structure and Biological Activity of Zn(II) Complex with Tris(benzimidazol-2-yl-methyl)amine Ligand
    刘小兰
    赵茹
    刘晓红
    岳俊杰
    尹宇新
    孙云
    孙命
    ChineseJournalofChemistry, 2004, (01) : 75 - 79
  • [44] Synthesis, Crystal Structure, and Properties of a Novel Copper(II) Complex with the Tripod Ligand Tris(2-benzimidazolylmethyl)amine
    Han, Xiangen
    Wei, Xianyong
    Wang, Xingyong
    Wei, Yakui
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (08) : 563 - 568
  • [45] NICKEL(II) AND COPPER(II) COMPLEXES OF TRIPOD LIGAND TRIS(2-BENZIMIDAZYLMETHYL)AMINE
    THOMPSON, LK
    RAMASWAMY, BS
    DAWE, RD
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1978, 56 (10): : 1311 - 1318
  • [46] Synthesis, Spectrothermal and Structural Characterization of Saccharinatobis(tris-hydroxymethylaminomethane)zinc(II) saccharinate Complex, [Zn(sac)(tham)2](sac)
    Pasaoglu, Humeyra
    Heren, Zerrin
    Kastas, Gokhan
    Akdag, Kamber
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2009, 65 : S279 - S279
  • [47] Synthesis, spectrothermal and structural characterization of saccharinatobis(tris-hydroxymethylaminomethane)zinc(II)saccharinate complex, [Zn(sac)(tham)2](sac)
    Heren, Zerrin
    Pasaoglu, Huemeyra
    Kastas, Goekhan
    Akdag, Kamber
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (11): : 1933 - 1936
  • [48] Copper(II) complex of the tripodal ligand tris((benzimidazol-2-yl)methyl)amine and its bonding to a sulfur ligand of thiolate character
    Sletten, J
    Grove, H
    ACTA CHEMICA SCANDINAVICA, 1997, 51 (08): : 822 - 831
  • [49] Tris(1-propan-2-onyl oxime)amine
    Goldcamp, MJ
    Bauer, JAK
    Baldwin, MJ
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : O1354 - O1355
  • [50] Synthesis and structural characterization of monomeric zinc(II), cadmium(II), and mercury(II) arenethiolates with a chelating oxazoline ligand
    Mugesh, G
    Singh, HB
    Butcher, RJ
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 1999, (08) : 1229 - 1236
12345