Structural characterization of a zinc(II) complex of a tris(oxime)amine ligand

被引：10
|
作者：
Goldcamp, MJ [1 ]
Bauer, JAK [1 ]
Baldwin, MJ [1 ]
机构：
[1] Univ Cincinnati, Dept Chem, Cincinnati, OH 45221 USA
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2005年 / 35卷 / 01期
关键词：
diacetato-(tris(1-propan-2-onyl oxime)amine)zinc(II); diacetato-(tris(2-hydroxyliminopropyl)amine)zinc(II); X-ray crystal structure; synthesis;
D O I：
10.1007/s10870-005-1158-3
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The ligand tris(1-propan-2-onyl oxime)amine (TRISOXH3) binds to zinc(II) acetate as a tridentate N-3 donor, with a third oxime group remaining unbound and extending into the crystal lattice. The crystal structure shows a distorted trigonal bipyramidal geometry around the zinc center. An intramolecular hydrogen bonding interaction between a coordinated oxime donor and an oxygen of a bound acetate is observed. This structure is similar to that of a previously reported zinc(II) complex of a related bis(oxime)amine ligand. However, the structure of Zn(TRISOXH3)(OAc)(2) is different in ligand coordination mode and metal coordination number from those of the previously reported complexes Ni(TRISOXH3)Cl-2 or [Ni(TRISOXH3)(NO3)(H2O)]NO3.
引用
收藏
页码：77 / 83
页数：7
相关论文
共 50 条
  • [11] SYNTHESIS AND PROPERTIES OF COBALT AND NICKEL-COMPLEXES WITH TRIPOD LIGAND TRIS(2-DIPHENYLARSINOETHYL)AMINE - STRUCTURAL CHARACTERIZATION OF A DELTA-PHENYL COMPLEX OF NICKEL(II) WITH SAME LIGAND
    SACCONI, L
    DAPPORTO, P
    STOPPIONI, P
    INORGANIC CHEMISTRY, 1976, 15 (02) : 325 - 329
  • [12] Synthesis and Structural Characterization of Five-Coordinate Cobalt(II) Complexes Based on tris(2-Benzimidazolymethyl)amine Ligand
    Ge, Chun-Hua
    Li, Li-Hua
    Wang, Ying-Qi
    Zhang, Rui
    Zhang, Xiang-Dong
    ASIAN JOURNAL OF CHEMISTRY, 2014, 26 (16) : 5093 - 5096
  • [13] Synthesis and oxidation studies of a copper complex with a tris-oxime ligand
    O'Connor, Ryan T.
    Davis, Craig M.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 245
  • [14] UNUSUAL COORDINATION IN A COBALT(II) COMPLEX WITH TRIPOD LIGAND TRIS(2-DIPHENYLPHOSPHINOETHYL)AMINE
    SACCONI, L
    DIVAIRA, M
    BIANCHI, A
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (14) : 4465 - &
  • [15] Studies on Copper(II) Perchlorate Complex with Tripod Ligand Tris(2-benzimidazolylmethyl)amine
    Han, Xiangen
    Wei, Xianyong
    Wang, Xingyong
    Wang, Xiao
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (10) : 821 - 825
  • [16] Synthesis and Structural Characterization of the Schiff Base Zn(II) Complex from Salicylaldehyde and Tris(2-aminoethyl)amine
    R. Ranjineh Khojasteh
    S. Jalali Matin
    Crystallography Reports, 2018, 63 : 1138 - 1142
  • [17] Synthesis and Structural Characterization of the Schiff Base Zn(II) Complex from Salicylaldehyde and Tris(2-aminoethyl)amine
    Khojasteh, R. Ranjineh
    Matin, S. Jalali
    CRYSTALLOGRAPHY REPORTS, 2018, 63 (07) : 1138 - 1142
  • [18] Developing theoretical models of nickel(II) tris(oxime)amine complexes.
    Jones, RM
    Baldwin, MJ
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U1548 - U1548
  • [19] Synthesis, characterization and structural study of new nickel(II) and mercury (II) complexes with imidazole oxime ligand
    Bouchouit, Mehdi
    Belahlou, Hadjer
    Guergouri, Mounia
    Bensegueni, Rafik
    Bouacida, Sofiane
    Bendeif, El-Eulmi
    Bouchouit, Karim
    Bouraiou, Abdelmalek
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1287
  • [20] Synthesis, Crystal Structures and Characterization of Zinc(II) Complexes with the Tripod Ligand Tris(N-methylbenzimidazol-2-ylmethyl)amine and α, β-Unsaturated Carboxylates
    Wu, Huilu
    Ying, Wei
    Fan, Xuyang
    Sun, Qingyu
    Qi, Baoliang
    Xu, Yuhao
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2009, 39 (05) : 250 - 255
12345