Synthesis and structure of the coordination polymer [Li5/3H1/3(H4chhc)]

被引:0
|
作者
Aliev, S. B. [1 ]
Samsonenko, D. G. [1 ,2 ]
Fedin, V. P. [1 ,2 ]
机构
[1] Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
基金
俄罗斯基础研究基金会;
关键词
lithium; coordination polymers; metal-organic frameworks; cyclohexanehexacarboxylic acid; X-ray crystallography; METAL; HYDROGEN; STORAGE; DESIGN;
D O I
10.1007/s11172-014-0539-1
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The coordination polymer of the composition [Li5/3H1/3(H(4)chhc)] was synthesized by the reaction of lithium hydroxide monohydrate with 1,2,3,4,5,6-cyclohexanehexacarboxylic acid (H(6)chhc) at 100 degrees C in a 1,4-dioxane-methanol mixture. The structure of this compound was determined by X-ray crystallography and confirmed by IR spectroscopy, as well as by thermogravimetric and elemental analysis. The coordination polymer has a structure of a 3D metal-organic framework built from lithium cations and H(4)chhc(2-) anions.
引用
收藏
页码:997 / 1000
页数:4
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