Kinetics of homogeneous acetoxylation of cyclododecene and 1,5,9-cyclododecatriene catalyzed by Pd(OAc)2

被引：3
|
作者：
Balbolov, E [1 ]
Dimitrov, SD
机构：
[1] Zlatarov Univ, Dept Organ Synth, Bourgas 8010, Bulgaria
[2] Zlatarov Univ, Dept Chem Engn, Bourgas 8010, Bulgaria
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 1997年 / 62卷 / 02期
关键词：
acetoxylation; Pd(OAc)(2); cyclododecene; 1,5,9-cyclododecatriene;
D O I：
10.1007/BF02475468
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of acetoxylation of cyclododecene and (E,E,E)-1,5,9-cyclododecatriene catalyzed by Pd(OAc)(2) has been studied in glacial acetic acid solutions at 323-343 K and atmospheric pressure. The experimental data were described by kinetic equations of the Michaelis - Menten type.
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页码：305 / 311
页数：7
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