Palladium(II)-catalysed oxidation of (E,E,Z)-1,5,9-cyclododecatriene

被引：0
|
作者：
Balbolov, E
Skumov, M
Kotov, S
机构：
[1] Prof Assen Zlatarov Univ, Dept Organ Chem Technol, Burgas 8010, Bulgaria
[2] Prof Assen Zlatarov Univ, Dept Organ Chem, Burgas 8010, Bulgaria
来源：
OXIDATION COMMUNICATIONS | 2003年 / 26卷 / 02期
关键词：
oxidation; Pd(II) salts; (E,E,Z)-1,5,9-cyclododecatriene;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The oxidation of (E,E,Z)-1,5,9-cyclododecatriene catalysed by Pd(II)-Cu(II) system has been studied at temperature 373 K and 2.5 MPa air pressure in alcoholic solution. Use of aliphatic alcohols both. as solvents and reactants resulted in high selectivities with respect to allyl ethers and ketones while maintaining relatively high cyclododecatriene conversion. A reaction network was presented that explains both the results of this work and earlier results from literature.
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页码：193 / 197
页数：5
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