Mass spectral studies of 1-(2-chloroethoxy)-2-[(2-chloroethyl)thio]ethane and related compounds using gas chromatography-mass spectrometry (GC-MS) and gas chromatography-triple quad mass spectrometry (GC-QQQ)

被引：1

作者：

Hsu, Fu-Lian ^{[1
]}

Winemiller, Mark D. ^{[1
]}

Bae, Su Y. ^{[1
]}

机构：

[1] US Army, ECBC, Res & Technol Directorate, Gunpowder, MD 21010 USA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2016年 / 191卷 / 06期

关键词：

Sulfur mustard; degradation products; gas chromatography; tandem mass spectrometry; fragmentation; METASTABLE ION CHARACTERISTICS; MUSTARD HYDROLYSIS PRODUCTS; 2-CHLOROETHYL ETHYL SULFIDE; SULFUR VESICANTS; ELECTRON-IMPACT; COLLISIONAL ACTIVATION; RETENTION INDEXES; DEGRADATION; SULPHOXIDES; SULPHONES;

D O I：

10.1080/10426507.2015.1119145

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electron impact and collision-ion-dissociation mass spectra of 1-(2-chloroethoxy)-2-[(2-chloroethyl) thio]ethane (1) and 10 related molecules were obtained using gas chromatography-mass spectrometry and gas chromatography-triple quad mass spectrometry. These mass spectral studies were performed to facilitate the development of a spectral database of mustard-related compounds for verification purposes of the Chemical Weapons Convention. The proposed fragmentation pathways of each individual molecule (1-11) are reported along with rationalizations for the most characteristic ions.

引用

页码：958 / 964

页数：7

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