Mass spectral studies of 1-(2-chloroethoxy)-2-[(2-chloroethyl)thio]ethane and related compounds using gas chromatography-mass spectrometry (GC-MS) and gas chromatography-triple quad mass spectrometry (GC-QQQ)

被引：1

作者：

Hsu, Fu-Lian ^{[1
]}

Winemiller, Mark D. ^{[1
]}

Bae, Su Y. ^{[1
]}

机构：

[1] US Army, ECBC, Res & Technol Directorate, Gunpowder, MD 21010 USA

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2016年 / 191卷 / 06期

关键词：

Sulfur mustard; degradation products; gas chromatography; tandem mass spectrometry; fragmentation; METASTABLE ION CHARACTERISTICS; MUSTARD HYDROLYSIS PRODUCTS; 2-CHLOROETHYL ETHYL SULFIDE; SULFUR VESICANTS; ELECTRON-IMPACT; COLLISIONAL ACTIVATION; RETENTION INDEXES; DEGRADATION; SULPHOXIDES; SULPHONES;

D O I：

10.1080/10426507.2015.1119145

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electron impact and collision-ion-dissociation mass spectra of 1-(2-chloroethoxy)-2-[(2-chloroethyl) thio]ethane (1) and 10 related molecules were obtained using gas chromatography-mass spectrometry and gas chromatography-triple quad mass spectrometry. These mass spectral studies were performed to facilitate the development of a spectral database of mustard-related compounds for verification purposes of the Chemical Weapons Convention. The proposed fragmentation pathways of each individual molecule (1-11) are reported along with rationalizations for the most characteristic ions.

引用

页码：958 / 964

页数：7

共 50 条

[21] COMPARISON OF METHODS FOR THE MEASUREMENT OF PLASMA THEOPHYLLINE .1. GAS CHROMATOGRAPHY-MASS SPECTROMETRY (GC-MS)
LARTIGUEMATTEI, C
CHABARD, JL
BERGER, JA
ANNALES DE BIOLOGIE CLINIQUE, 1982, 40 (04) : 487 - 487
[22] Forensic Evaluation of Ink Age by Raman Spectroscopy and Gas Chromatography-Mass Spectrometry (GC-MS)
Guo, Chao
Hao, Mingyang
Liu, Shuo
Lv, Jungang
ANALYTICAL LETTERS, 2025, 58 (04) : 656 - 662
[23] The Simultaneous measurement of serum testosterone and 5α-dihydrotestosterone by gas chromatography-mass spectrometry (GC-MS)
Kannenberg, Frank
Fobker, Manfred
Schulte, Erhard
Pierscinski, Grzegorz
Kelsch, Reinhard
Zitzmann, Michael
Nofer, Jerzy-Roch
Schuering, Andreas N.
CLINICA CHIMICA ACTA, 2018, 476 : 15 - 24
[24] Preparation of Drosophila Larval Samples for Gas Chromatography-Mass Spectrometry (GC-MS)-based Metabolomics
Li, Hongde
Tennessen, Jason M.
JOVE-JOURNAL OF VISUALIZED EXPERIMENTS, 2018, (136):
[25] Extraction of pure components from overlapped signals in gas chromatography-mass spectrometry (GC-MS)
Vladimir A Likić
BioData Mining, 2
[26] Analysis of Organic Acids from Lactobacillus plantarum with Gas Chromatography-Mass Spectrometry (GC-MS)
Basa, E. L. U.
Julendra, H.
Abinawanto, A.
Sofyan, A.
Sophian, A.
PROCEEDINGS OF THE 4TH INTERNATIONAL SYMPOSIUM ON CURRENT PROGRESS IN MATHEMATICS AND SCIENCES (ISCPMS2018), 2019, 2168
[27] Gas Chromatography-Mass Spectrometry (GC-MS) Analysis of Volatile Components from Guava Leaves
Xu, Chang
Liang, Zhengang
Tang, Dan
Xiao, Tongjie
Tsunoda, Makoto
Zhang, Yingxia
Zhao, Lini
Deng, Shiming
Song, Yanting
JOURNAL OF ESSENTIAL OIL BEARING PLANTS, 2017, 20 (06) : 1536 - 1546
[28] Simultaneous determination of 19 bromophenols by gas chromatography-mass spectrometry (GC-MS) after derivatization
Liu, Yanwei
Hou, Xingwang
Li, Xiaoying
Liu, Jiyan
Jiang, Guibin
TALANTA, 2024, 274
[29] WiPP: Workflow for Improved Peak Picking for Gas Chromatography-Mass Spectrometry (GC-MS) Data
Borgsmueller, Nico
Gloaguen, Yoann
Opialla, Tobias
Blanc, Eric
Sicard, Emilie
Royer, Anne-Lise
Le Bizec, Bruno
Durand, Stephanie
Migne, Carole
Petera, Melanie
Pujos-Guillot, Estelle
Giacomoni, Franck
Guitton, Yann
Beule, Dieter
Kirwan, Jennifer
METABOLITES, 2019, 9 (09)
[30] Assessment of sampling strategies for gas chromatography-mass spectrometry (GC-MS) based metabolomics of cyanobacteria
Krall, Leonard
Huege, Jan
Catchpole, Gareth
Steinhauser, Dirl
Willmitzer, Lothar
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES, 2009, 877 (27): : 2952 - 2960

← 1 2 3 4 5 →