Synthesis, Isolation and Structure of Trifluoromethylated Fullerene D3-C78, C78(1)(CF3)10-18

被引：9

作者：

Kosaya, Maria P. ^{[1
]}

Fritz, Maria A. ^{[1
]}

Brotsman, Victor A. ^{[1
]}

Tamm, Nadezhda B. ^{[1
]}

Ignat'eva, Daria V. ^{[1
]}

Troyanov, Sergey I. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

addition patterns; C-78; isomers; higher fullerenes; structure elucidation; trifluoromethylation; CAGE ISOMERS; X-RAY; DERIVATIVES; C-78; REARRANGEMENTS; C-78(2)CL-30; CHLORIDES; C-90;

D O I：

10.1002/asia.201600094

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-temperature trifluoromethylation of fullerene C-78 followed by HPLC separation of C-78(CF3)(n) derivatives resulted in the isolation and X-ray structural characterization of 15 compounds, that is, two C-78(1)(CF3)(10), three C-78(1)(CF3)(12), four C-78(1)(CF3)(14), and five C-78(1)(CF3)(16) isomers as well as one isomer of C-78(1)(CF3)(18). The addition patterns of the C-78(1)(CF3)(n) molecules are discussed in terms of trifluoromethylation pathways and relative formation energies.

引用

页码：1000 / 1003

页数：4

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