Synthesis, Isolation and Structure of Trifluoromethylated Fullerene D3-C78, C78(1)(CF3)10-18

被引：9

作者：

Kosaya, Maria P. ^{[1
]}

Fritz, Maria A. ^{[1
]}

Brotsman, Victor A. ^{[1
]}

Tamm, Nadezhda B. ^{[1
]}

Ignat'eva, Daria V. ^{[1
]}

Troyanov, Sergey I. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2016年 / 11卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

addition patterns; C-78; isomers; higher fullerenes; structure elucidation; trifluoromethylation; CAGE ISOMERS; X-RAY; DERIVATIVES; C-78; REARRANGEMENTS; C-78(2)CL-30; CHLORIDES; C-90;

D O I：

10.1002/asia.201600094

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High-temperature trifluoromethylation of fullerene C-78 followed by HPLC separation of C-78(CF3)(n) derivatives resulted in the isolation and X-ray structural characterization of 15 compounds, that is, two C-78(1)(CF3)(10), three C-78(1)(CF3)(12), four C-78(1)(CF3)(14), and five C-78(1)(CF3)(16) isomers as well as one isomer of C-78(1)(CF3)(18). The addition patterns of the C-78(1)(CF3)(n) molecules are discussed in terms of trifluoromethylation pathways and relative formation energies.

引用

页码：1000 / 1003

页数：4

共 50 条

[31] Synthesis and X-ray structure of C2-C96(176)(CF3)18
Tamm, Nadezhda B.
Scheurell, Kerstin
Kemnitz, Erhard
Troyanov, Sergey I.
MENDELEEV COMMUNICATIONS, 2015, 25 (04) : 275 - 276
[32] Trifluoromethyl derivatives of fullerene C76, C76(CF3)14-18
Tamm, Nadezhda B.
Troyanov, Sergey I.
MENDELEEV COMMUNICATIONS, 2010, 20 (04) : 229 - 230
[33] A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12
Tamm, Nadezhda B.
Troyanov, Sergey I.
MENDELEEV COMMUNICATIONS, 2016, 26 (04) : 312 - 313
[34] Trifluoromethyl derivatives of insoluble small-HOMO LUMO-gap hollow higher fullerenes. NMR and DFT structure elucidation of C2-(C 74-D3h)(CF3)12, C s-(C76-Td(2))(CF3)12, C2-(C78-D3h(5))(CF3)12
Shustova, Natalia B.
Kuvychko, Igor V.
Bolskar, Robert D.
Seppelt, Konrad
Strauss, Steven H.
Popov, Alexey A.
Boltalina, Olga V.
Journal of the American Chemical Society, 2006, 128 (49): : 15793 - 15798
[35] Trifluoromethyl derivatives of insoluble small-HOMO-LUMO-gap hollow higher fullerenes.: NMR and DFT structure elucidation of C2-(C74-D3h)(CF3)12, Cs-(C76-Td(2))(CF3)12, C2-(C78-D3h(5))(CF3)12, Cs-(C80-C2v(5)) (CF3)12, and C2-(C82-C2(5))(CF3)12
Shustova, Natalia B.
Kuvychko, Igor V.
Bolskar, Robert D.
Seppelt, Konrad
Strauss, Steven H.
Popov, Alexey A.
Boltalina, Olga V.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (49) : 15793 - 15798
[36] Synthesis, Isolation, and Structural Study of Trifluoromethyl Derivatives of the IPR Isomer of C84 Fullerene, C84(11)(CF3)14,16,18
Tamm, Nadezhda B.
Fritz, Maria A.
Romanova, Natalia A.
Markov, Vitaliy Yu.
Goryunkov, Alexey A.
Troyanov, Sergey I.
CHEMISTRYSELECT, 2022, 7 (44):
[37] Large Metal Ions in a Relatively Small Fullerene Cage: The Structure of Gd3N@C2(22010)-C78 Departs from the Isolated Pentagon Rule
Beavers, Christine M.
Chaur, Manuel N.
Olmstead, Marilyn M.
Echegoyen, Luis
Balch, Alan L.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (32) : 11519 - 11524
[38] CF2-Functionalized Trifluoromethylated Fullerene C70(CF3)8(CF2): Structure, Electronic Properties, and Spontaneous Oxidation at the Bridgehead Carbon Atoms
Lukonina, Natalia S.
Semivrazhskaya, Olesya O.
Apenova, Marina G.
Belov, Nikita M.
Troyanov, Sergey, I
Goryunkov, Alexey A.
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2019, 8 (10) : 1924 - 1932
[39] New Trifluoromethylated Derivatives of Metal Nitride Clusterfullerenes: Sc3N@Ih-C80(CF3)14 and Sc3N@D5h-C80(CF3)16
Wei, Tao
Tamm, Nadezhda B.
Yang, Shangfeng
Troyanov, Sergey I.
CHEMISTRY-AN ASIAN JOURNAL, 2014, 9 (09) : 2449 - 2452
[40] Synthesis, Isolation, Characterization, and Theoretical Studies of Sc3NC@C78-C2
Wu, Jingyi
Wang, Taishan
Ma, Yihan
Jiang, Li
Shu, Chunying
Wang, Chunru
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (48): : 23755 - 23759

← 1 2 3 4 5 →