Rhenium(V) complexes with 2-mercaptoimidazole

被引：0

作者：

Amindzhanov, AA ^{[1
]}

Orifov, AA ^{[1
]}

Safarmamadov, SM ^{[1
]}

机构：

[1] Tajik State Natl Univ, Dushanbe, Tajikistan

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 50卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Optimum conditions for the synthesis of mono-, di-, and tetrasubstituted complexes of rhenium(V) with 2-mercaptoimidazole are developed. The sulfur atom of the thione group in a 2-mercaptoimidazole molecule is found to coordinate with rhenium(V). The number of water molecules of crystallization in the complexes increases with an increase in the number of coordinated 2-mercaptoimidazole molecules. The nature of the halide ion and the number of coordinated 2-mercaptoimidazole molecules affect the thermolysis onset temperature of the complexes.

引用

页码：45 / 49

页数：5

共 50 条

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