A green approach for arylation of phenols using iron catalysis in water under aerobic conditions

被引：24
|
作者：
Sindhu, Kallikkakam S. [1 ]
Ujwaldev, Sankuviruthiyil M. [1 ]
Krishnan, K. Keerthi [1 ]
Anilkumar, Gopinathan [1 ,2 ]
机构：
[1] Mahatma Gandhi Univ, Sch Chem Sci, PD Hills PO, Kottayam 686560, Kerala, India
[2] Mahatma Gandhi Univ, AMMRC, PD Hills PO, Kottayam 686560, Kerala, India
来源：
JOURNAL OF CATALYSIS | 2017年 / 348卷
关键词：
Iron catalysis; Etherification; C-O coupling; Green chemistry; Water; FeCl3; CROSS-COUPLING REACTION; O BOND FORMATION; ARYL HALIDES; PALLADIUM; IODIDES; NANOPARTICLES; CHLORIDES; ALCOHOLS; ALKYNES; ETHERS;
D O I：
10.1016/j.jcat.2017.02.010
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The first efficient iron-catalyzed coupling of aryl iodides with phenols was developed exclusively with water as solvent. The reaction is performed with low cost and readily available FeCl3 center dot 6H(2)O and DMEDA catalytic system providing diaryl ethers in good to excellent yields. The effectiveness of this reaction was further revealed by compatibility with a wide range of functional groups. Moreover, the procedure is rendered simple as this transformation is carried out in the presence of air. Thus, the protocol represents a facile, economical and eco-friendly procedure to access diaryl ethers. (C) 2017 Elsevier Inc. All rights reserved.
引用
收藏
页码：146 / 150
页数：5
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