A green approach for arylation of phenols using iron catalysis in water under aerobic conditions

被引:24
|
作者
Sindhu, Kallikkakam S. [1 ]
Ujwaldev, Sankuviruthiyil M. [1 ]
Krishnan, K. Keerthi [1 ]
Anilkumar, Gopinathan [1 ,2 ]
机构
[1] Mahatma Gandhi Univ, Sch Chem Sci, PD Hills PO, Kottayam 686560, Kerala, India
[2] Mahatma Gandhi Univ, AMMRC, PD Hills PO, Kottayam 686560, Kerala, India
关键词
Iron catalysis; Etherification; C-O coupling; Green chemistry; Water; FeCl3; CROSS-COUPLING REACTION; O BOND FORMATION; ARYL HALIDES; PALLADIUM; IODIDES; NANOPARTICLES; CHLORIDES; ALCOHOLS; ALKYNES; ETHERS;
D O I
10.1016/j.jcat.2017.02.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The first efficient iron-catalyzed coupling of aryl iodides with phenols was developed exclusively with water as solvent. The reaction is performed with low cost and readily available FeCl3 center dot 6H(2)O and DMEDA catalytic system providing diaryl ethers in good to excellent yields. The effectiveness of this reaction was further revealed by compatibility with a wide range of functional groups. Moreover, the procedure is rendered simple as this transformation is carried out in the presence of air. Thus, the protocol represents a facile, economical and eco-friendly procedure to access diaryl ethers. (C) 2017 Elsevier Inc. All rights reserved.
引用
收藏
页码:146 / 150
页数:5
相关论文
共 50 条
  • [11] Approach of electrochemical synthesis of ammonia from water and nitrogen using iron under ambient conditions
    Jeon, Seok Hwan
    Kim, Kwiyong
    Kim, Jong-Nam
    Yoon, Hyung Chul
    Han, Jong-In
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
  • [12] REGIOSELECTIVE ARYLATION OF UNSATURATED SILANES UNDER PHASE-TRANSFER CATALYSIS CONDITIONS
    CHISTOVALOVA, NM
    AKHREM, IS
    SIZOI, VF
    BARDIN, VV
    VOLPIN, ME
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (05): : 1039 - 1042
  • [13] Multicomponent Approach Towards the Synthesis of Substituted Pyrroles under Supramolecular Catalysis Using β-Cyclodextrin as a Catalyst in Water Under Neutral Conditions
    Murthy, Sabbavarapu Narayana
    Madhav, Bandaru
    Kumar, Akkiligunta Vijay
    Rao, Kakulapati Rama
    Nageswar, Yadavalli Venkata Durga
    HELVETICA CHIMICA ACTA, 2009, 92 (10) : 2118 - 2124
  • [14] Aerobic Partial Oxidation of Alkanes Using Photodriven Iron Catalysis
    Coutard, Nathan
    Goldberg, Jonathan M.
    Valle, Henry U.
    Cao, Yuan
    Jia, Xiaofan
    Jeffrey, Philip D.
    Gunnoe, T. Brent
    Groves, John T.
    INORGANIC CHEMISTRY, 2022, 61 (02) : 759 - 766
  • [15] Acetylation of alcohols and phenols under solvent-free conditions using iron zirconium phosphate
    Hajipour, Abdol R.
    Karimi, Hirbod
    Masti, Amir
    CHINESE JOURNAL OF CATALYSIS, 2015, 36 (04) : 595 - 602
  • [16] Boosting photobioredox catalysis by morpholine electron donors under aerobic conditions
    Goncalves, Leticia C. P.
    Mansouri, Hamid R.
    PourMehdi, Shads
    Abdellah, Mohamed
    Fadiga, Bruna S.
    Bastos, Erick L.
    Sa, Jacinto
    Mihovilovic, Marko D.
    Rudroffe, Florian
    CATALYSIS SCIENCE & TECHNOLOGY, 2019, 9 (10) : 2682 - 2688
  • [17] Pd-catalyzed arylation of linear and angular spirodiamine salts under aerobic conditions
    Reilly, Sean W.
    Bryan, Nikaela W.
    Mach, Robert H.
    TETRAHEDRON LETTERS, 2017, 58 (05) : 466 - 469
  • [18] Water Oxidation Catalysis with Nonheme Iron Complexes under Acidic and Basic Conditions: Homogeneous or Heterogeneous?
    Hong, Dachao
    Mandal, Sukanta
    Yamada, Yusuke
    Lee, Yong-Min
    Nam, Wonwoo
    Llobet, Antoni
    Fukuzumi, Shunichi
    INORGANIC CHEMISTRY, 2013, 52 (16) : 9522 - 9531
  • [19] Palladium-catalyzed arylation of hydrophosphoryl compounds under conditions of phase transfer catalysis
    M. M. Kabachnik
    M. D. Solntseva
    I. P. Beletskaya
    Russian Chemical Bulletin, 1997, 46 : 1491 - 1491
  • [20] Palladium-catalyzed arylation of hydrophosphoryl compounds under conditions of phase transfer catalysis
    Kabachnik, MM
    Solntseva, MD
    Beletskaya, IP
    RUSSIAN CHEMICAL BULLETIN, 1997, 46 (08) : 1491 - 1491