Model systems for the CO-releasing flavonol 2,4-dioxygenase enzyme

被引：56
|
作者：
Pap, Jozsef Sandor [1 ]
Kaizer, Jozsef [1 ]
Speier, Gabor [1 ]
机构：
[1] Univ Pannonia, Dept Chem, H-8201 Veszprem, Hungary
来源：
COORDINATION CHEMISTRY REVIEWS | 2010年 / 254卷 / 7-8期
关键词：
Bioinorganic chemistry; CO-releasing dioxygenases; Flavonol; Copper; Biomimetic oxygenation; DEPENDENT QUERCETIN 2,3-DIOXYGENASE; CRYSTAL-STRUCTURE; ASPERGILLUS-FLAVUS; O-BS; STOICHIOMETRIC OXYGENATION; CATALYZED OXYGENATION; FUNCTIONAL-ANALYSIS; MECHANISM; COPPER; COMPLEXES;
D O I：
10.1016/j.ccr.2009.11.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this review structural and reactivity studies on the co-ligand containing model complexes for the flavonol 2,4-dioxygenase (FDO) are covered. The main focus is on the relationship between the structural features of the copper-containing model complexes, and their activity in the enzyme-like reactions. Some radical initiated reactions and catalytic systems will also be discussed. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：781 / 793
页数：13
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