Solvothermal Synthesis and Structure of the [Ge2Se7]4- Anion in (enH2)[{Mn(en)2(enH)}2(μ-en)](Ge2Se7)2 and [Mn(dien)2]2Ge2Se7

被引：18
|
作者：
van Almsick, T [1 ]
Loose, A [1 ]
Sheldrick, WS [1 ]
机构：
[1] Ruhr Univ Bochum, Lehrstuhl Analyt Chem, D-44780 Bochum, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 01期
关键词：
germanium; selenium; chalcogenidometalates; crystal structure; solvothermal synthesis;
D O I：
10.1002/zaac.200400409
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
(enH(2))[{Mn(en)(2)(enH)}(2)(mu-en)](Ge2Se7)(2) (1) and [Mn(dien)(2)](2)Ge2Se7 (2) can be prepared by solvothermal reaction of elemental Ge and Se with Mn(OOCCH3)(2).4H(2)O in respectively superheated ethylenediamine/methanol (3:2 mixture, 150degrees) and di-ethylenetriamine (dien, 130 degreesC). The cyclic Ge2Se74- anion contains two tetrahedral GeSe4 building units linked at one corner Se atom and through an Se-Se bond. 1 also contains a novel complex cation in which Mn(II) atoms are coordinated by one terminal, one bridging and two chelating en ligands.
引用
收藏
页码：21 / 23
页数：3
相关论文
共 50 条
  • [41] AG2SE/GE-SE RESIST SYSTEMS
    VADIMSKY, RG
    TAI, KL
    ONG, E
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1982, 129 (03) : C96 - C96
  • [42] [Ga(en)3][Ga3Se7(en)] • H2O:: A gallium chalcogenide with chains of [Ga3Se6Se2/2(en)]3- bicycles
    Fehlker, A
    Blachnik, R
    Reuter, H
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (07): : 1225 - 1228
  • [43] Enthalpic relaxation in Ge2Sb2Se5 glass
    Svoboda, Roman
    Honcova, Pavla
    Malek, Jiri
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2012, 358 (04) : 804 - 809
  • [44] ON NA6GE2SE7, THE 1ST SELENIDOSOROGERMANATE(IV)
    EISENMANN, B
    HANSA, J
    SCHAFER, H
    REVUE DE CHIMIE MINERALE, 1986, 23 (01): : 8 - 13
  • [45] Mixed-valent selenidoantimonates(III,V) with transition-metal complexes as counterions:: Solvothermal syntheses and characterization of [M(dien)2]2Sb4Se9 (M = Mn, Fe), [Co(dien)2]2Sb2Se6, and [Ni(dien)2]2Sb2Se5
    Jia, Dingxian
    Zhang, Yong
    Zhao, Qianxin
    Deng, Jie
    INORGANIC CHEMISTRY, 2006, 45 (24) : 9812 - 9817
  • [46] CONDITIONS FOR THE FORMATION OF IN2CR2SE5 AND INCR4SE7
    KONESHOVA, TI
    KALINNIKOV, VT
    INORGANIC MATERIALS, 1985, 21 (03) : 324 - 327
  • [47] STRUCTURAL INVESTIGATIONS AND LUMINESCENCE OF IN2GE2O7 AND IN2SI2O7
    GAEWDANG, T
    CHAMINADE, JP
    GRAVEREAU, P
    GARCIA, A
    FOUASSIER, C
    POUCHARD, M
    HAGENMULLER, P
    JACQUIER, B
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1994, 620 (11): : 1965 - 1970
  • [48] Solvothermal synthesis and structures of lamellar [Mn(tren)2]Cl2 and the dimeric and polymeric hexaselenidomanganese(II) complexes [{Mn(Se6)(tren)}2] and ∞2[{Mn(Se6)(tren)}]
    Kromm, Anna
    Sheldrick, William S.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (04): : 529 - 532
  • [49] Synthesis and photoluminescence properties of In2Ge2O7 nanobelts
    Su, Yong
    Li, Sen
    Xu, Liang
    Chen, Yiqing
    Zhou, Qingtao
    Peng, Bo
    Yin, Song
    Meng, Xia
    Liang, Xuemei
    Feng, Yi
    NANOTECHNOLOGY, 2006, 17 (24) : 6007 - 6010
  • [50] Structural and magnetic properties of the layered manganese oxychalcogenides (LaO)2Mn2Se2O and (BaF)2Mn2Se2O
    Liu, R. H.
    Zhang, J. S.
    Cheng, P.
    Luo, X. G.
    Ying, J. J.
    Yan, Y. J.
    Zhang, M.
    Wang, A. F.
    Xiang, Z. J.
    Ye, G. J.
    Chen, X. H.
    PHYSICAL REVIEW B, 2011, 83 (17)
12345