Solvothermal Synthesis and Structure of the [Ge2Se7]4- Anion in (enH2)[{Mn(en)2(enH)}2(μ-en)](Ge2Se7)2 and [Mn(dien)2]2Ge2Se7

被引：18

作者：

van Almsick, T ^{[1
]}

Loose, A ^{[1
]}

Sheldrick, WS ^{[1
]}

机构：

[1] Ruhr Univ Bochum, Lehrstuhl Analyt Chem, D-44780 Bochum, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 01期

关键词：

germanium; selenium; chalcogenidometalates; crystal structure; solvothermal synthesis;

D O I：

10.1002/zaac.200400409

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(enH(2))[{Mn(en)(2)(enH)}(2)(mu-en)](Ge2Se7)(2) (1) and [Mn(dien)(2)](2)Ge2Se7 (2) can be prepared by solvothermal reaction of elemental Ge and Se with Mn(OOCCH3)(2).4H(2)O in respectively superheated ethylenediamine/methanol (3:2 mixture, 150degrees) and di-ethylenetriamine (dien, 130 degreesC). The cyclic Ge2Se74- anion contains two tetrahedral GeSe4 building units linked at one corner Se atom and through an Se-Se bond. 1 also contains a novel complex cation in which Mn(II) atoms are coordinated by one terminal, one bridging and two chelating en ligands.

引用

页码：21 / 23

页数：3

共 50 条

[31] Synthesis and High-Temperature Heat Capacity of Sm2Ge2O7 and Eu2Ge2O7
Denisova, L. T.
Irtyugo, L. A.
Kargin, Yu. F.
Beletskii, V. V.
Belousova, N. V.
Denisov, V. M.
INORGANIC MATERIALS, 2018, 54 (02) : 167 - 170
[32] Synthesis and High-Temperature Heat Capacity of Sm2Ge2O7 and Eu2Ge2O7
L. T. Denisova
L. A. Irtyugo
Yu. F. Kargin
V. V. Beletskii
N. V. Belousova
V. M. Denisov
Inorganic Materials, 2018, 54 : 167 - 170
[33] Synthesis, crystal structure and properties of [(dien)2Mn]Ge2S4 with mixed-valent Ge centers
Yue, Cheng-Yang
Yuan, Zhuang-Dong
Zhang, Lu-Ge
Wang, Ya-Bai
Liu, Guo-Dong
Gong, Liao-Kuo
Lei, Xiao-Wu
JOURNAL OF SOLID STATE CHEMISTRY, 2013, 206 : 129 - 133
[34] Hydrothermal Synthesis and Structure of a Novel Binuclear Molybdenum Complex with Oxalate Ligand, （enH2）{NH4[Co（en）3][Mo2O7（C2O4）] }2·2H2O
LIU Pei-De PEI Xiao-Ke LIN Bi-Zhou② (Institute of Materials Physical Chemistry
结构化学, 2004, (01) : 57 - 61
[35] SYNTHESIS OF THE MANGANATES SC2MN2O7, IN2MN2O7, Y2MN2O7, LU-TB2MN2O7
TROYANCHUK, IO
INORGANIC MATERIALS, 1990, 26 (02) : 376 - 377
[36] Hydrothermal synthesis and structure of a novel binuclear molybdenum complex with oxalate ligand, (enH2)[NH4[Co(en)3][Mo2O7(C2O4)] }2•2H2O
Liu, PD
Pei, XK
Lin, BZ
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (01) : 57 - 61
[37] Syntheses, crystal structures, and reactivity of [enH]4[Sn2Se6]•en, [enH]4[Sn2Te6]•en and [enH]4[Sn2S6]:: Known anions within novel coordination spheres obtained by novel synthesis routes
Dehnen, S
Zimmermann, C
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (11): : 2463 - 2469
[38] Crystallization processes in Ge2Sb2Se4Te glass
Svoboda, Roman
Bezdicka, Petr
Gutwirth, Jan
Malek, Jiri
MATERIALS RESEARCH BULLETIN, 2015, 61 : 207 - 214
[39] Investigation of the Structures and Chemical Bonding of Mn2Ge6-and Mn2Ge7-Clusters via Anion Photoelectron Spectroscopy and Theoretical Calculations
Zhao, Li-Juan
Xu, Hong-Guang
Xu, Xi-Ling
Zheng, Wei-Jun
INORGANIC CHEMISTRY, 2023, 62 (05) : 2033 - 2039
[40] Solvothermal Syntheses and Characterization of New Transition Metal Chalcogenidogermanates [{Co(tepa)}2(μ-Ge2S6)] and [{M(tepa)}2(μ-Ge2Se6)] (M = Mn, Fe) (tepa = Tetraethylenepentamine)
Chen, Jiang-Fang
Jin, Qin-Yan
Pan, Ying-Li
Zhang, Yong
Jia, Ding-Xian
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (01): : 230 - 235

← 1 2 3 4 5 →