Efficient syntheses of trans-(+)-laurediol from carbohydrate precursors

被引：8

作者：

Gadikota, RR ^{[1
]}

Keller, AI ^{[1
]}

Callam, CS ^{[1
]}

Lowary, TL ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

TETRAHEDRON-ASYMMETRY | 2003年 / 14卷 / 06期

关键词：

D O I：

10.1016/S0957-4166(03)00078-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two routes for the synthesis of the marine natural product trans-laurediol 6 are described. In the first approach 6 is obtained in ten steps and 21% overall yield from monoacetone D-glucose. The second route provides the target in eleven steps and 13% yield from D-mannose. Both routes are more efficient, both in terms of number of steps and overall yield, than previously reported syntheses. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：737 / 742

页数：6

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